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聚3，4-乙二氧噻吩包覆碳纳米管的原位化学氧化合成 被引量：2

Preparing Carbon Nanotubes Capsulated with Poly(3,4-ethylenedioxythiophene) by in-situ Polymerization
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摘要 报道了不同溶剂体系中原位化学氧化合成PEDOT/CNTs纳米复合物的实验,用红外光谱(IR)、拉曼光谱、透射电子显微镜(TEM)以及四探针电导率仪对合成的纳米复合物进行了表征,可以看出:采用乙腈作为反应介质环境,可以获得反应充分完全的具有理想形态的聚乙二氧噻吩包覆碳纳米管的纳米复合纤维;通过对合成纳米复合纤维进行导电性方面的表征,证明通过一维纳米形态的碳纳米管和导电聚乙二氧噻吩的复合,可以获得具有更高导电性的纳米复合纤维。 Carbon nanotubes capsulated with poly （3, 4-ethylenedioxythiophene） （simplified as PEDOT/CNTs） nanocomposite fibrils synthesized in different solvent media were reported and characterized by Fourier Transform Infrared （FTIR） spectroscopy, Raman spectroscopy,transmission electron microscopy and standard four-probe method. The results showed that PEDOT/CNTs nanocomposite fibrils with ideal morphology can be manufactured with acetonitrile as reaction medium as compared with water or ethanol as reaction medium. By means of characterizing conductivity of the as synthesized nanocomposite fibrils, it is demonstrated that nanocomposite fibrils with highly improved conductivity can be created by means of carbon nanotubes as in situ synthesis template.
作者 黄大庆 黄俊 哈恩华 刘旸 吕明云 丁鹤雁
机构地区 北京航空材料研究院 北京航空航天大学
出处 《材料工程》 EI CAS CSCD 北大核心 2008年第5期13-16,共4页 Journal of Materials Engineering
基金 航空基金资助项目(04G21008) 总装预研重点基金资助项目(6140510)
关键词 聚3 4-乙二氧噻吩(PEDOT) 碳纳米管(CNTs) 原位化学氧化合成 导电性 poly（3,4-ethylenedioxythiophene） carbon nanotube in-situ polymerization conductivity
分类号 O631 [理学—高分子化学]
  • 相关文献

参考文献9

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共引文献17

同被引文献28

  • 1吴晓晓,李福山,吴薇,郭太良.基于石墨烯/PEDOT∶PSS叠层薄膜的柔性OLED器件[J].发光学报,2014,35(4):486-490. 被引量：21
  • 2谢德明,胡吉明,童少平,王建明,张鉴清.富锌漆研究进展[J].中国腐蚀与防护学报,2004,24(5):314-320. 被引量：45
  • 3李金桂.无机富锌涂层的诞生和应用[J].防腐保温技术,2005,13(1):22-25. 被引量：2
  • 4Yun Dong-Jin, Ra Hyemln, Rhee Shi-Woo. Concentration effect of muhiwalled carbon nanotube and poly (3, 4-ethylenedioxythiophene) polymerized with poly (4-styrenesulfonate) conjugated film on the catalytic activity for counter electrode in dye sensitized solar cells[ J]. Renewable Energy,2013,50:692 - 700.
  • 5Li Jiao, Liu Jun-Cheng, Gao Cong-Jie. On the mechanism of conductivity enhancement in PEDOT/PSS film doped with multi-walled carbon nanotubes[J]. Journal of Polymer Research,2010,17:713 -718.
  • 6Zhang H, Hong X, Li H M, et al. Water-soluble multiwalled carbon nanotubes functionalized with sulfonated polyaniline [ J ]. Journal of Physical Chemistry B ,2006,110:9095 - 9099.
  • 7Kim Ki-Seok, Park Soo-Jin. Influence of dispersion of multi-walled carbon nanotubes on the electrochemical performance of PEDOT-PSS films[J]. Materials Science and Euglneering B ,2011,176:204 - 209.
  • 8Chen Y, Kang K S, Han K J, et al. Enhanced optical and electrical properties of PEDOT:PSS films by the addition of MWCNT-sorbitol[J]. Synthetic Met als 2009,159 : 1701 - 1704.
  • 9Chert Li, Yuan Changzhou, Dou Hui, et al. Synthesis and electrochemical capacitance of core-shell poly ( 3, 4-ethylenedioxythiophene )/poly (sodium 4-styrenesulfonate )-modified muhiwalled carbon nanotube nanocomposites[ J ]. Electrochimica Acta,2009 ,54 :2335 - 2341.
  • 10Wang J, Xu Y, Sun X, et al. Electrochemical capacitance of the composite of poly (3,4-ethylenedioxythiophene) and functionalized single-walled carbon nauotubes [ J ]. Journal of Solid State Electrochemistry,2008,12 ( 7 - 8 ) : 947 - 952.

引证文献2

二级引证文献9

材料工程
2008年 第5期

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