异氰酸与简单自由基反应的研究现状

The Present Studies on the Reaction of HNCO with Simple Radicals

目前对异氰酸(HNCO)反应的研究有很多,主要集中在HNCO与原子(H,O,N,F,Cl等)、双原子分子和双原子自由基(OH,NH,CH,CF,CCl,CN等)、多原子分子和自由基(HCO,NH2,CHX等)的反应.笔者就以上反应在实验和理论方面进行了综述.

A lot of researches have been done on the reaction of isocyanic acid （HNCO） with simple radicals. The researches focus on the reactions of HNCO with some single atoms （H, O, N, F, Cl etc）, some two-atom molecules and radicals （OH, NH, CH, CF, CCl, CN, CO etc）, three-atom molecules and radicals （HCO, NH2, CHX, NO2, CF2, CCl2 etc） and many-atom molecules and radicals. Some reactions of HNCO with single atoms, two-atom molecules and radicals and many-atom radicals are reviewed.