期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

含二茂铁盘状主体的阴离子识别与电化学传感 被引量：1

Anion Recognition and Electrochemical Sensing of Podands Containing Ferrocenyl Species
下载PDF
导出
摘要 合成了两个新的具有两条或三条苯并咪唑阳离子臂的盘状主体分子1和2,利用核磁滴定和微分极谱测定了主体分子对氯、溴、碘等阴离子的识别性能和电化学响应.结果表明,主体1和2与客体阴离子之间形成(C(H)+…X-氢键作用,阴离子位于主体构象变化所围成的锥形空穴中,形成1∶1型的超分子配合物.识别阴离子时多重氢键作用使主体分子1表现出显著的化学位移和电化学响应. Benzene-based bipodal and tripodal electrochemical-responsive receptors 1 and 2 with ferrocenyl arms comprising benzoimidazolium moieties were synthesized and structurally characterized. The interactions between receptors and anions such as Cl^- , Br and I^- were investigated by ^1 H NMR titration in d6-DMSO and differential pulse voltammetry. Results indicated that the recognition of the host is introduced by the presence of directional hydrogen-bonding （C（H） ~ functionality as well as the electrostatic force between the benzoimidazolium moieties and the anion. The 1 ： 1 model supramolecular complex is formed between host and guest molecule. Multiform hydrogen bonds are important for the receptor 1 exhibiting more efficient binding electrochemical signal transduction.
作者 柏 张福莲 党东宾 高慧
机构地区 河南大学化学化工学院分子与晶体工程研究所
出处 《河南大学学报（自然科学版）》 CAS 北大核心 2008年第3期251-255,共5页 Journal of Henan University:Natural Science
基金 国家自然科学基金(20701012) 教育部科学技术研究重点项目(207068) 河南大学自然科学基金资助项目(06YBZR017)
关键词 阴离子识别 主体 氢键 电化学 anion recognition receptor hydrogen bonding electrochemistry
分类号 O646.5 [理学—物理化学]
  • 相关文献

参考文献16

  • 1Schmidtchen F P. Reflections on the construction of anion receptors is there a sign to resign from design [J]. Coord Chem Rev, 2006, 250: 2918-2928.
  • 2Beer P D, Gale P A. Anion recognition and sensing: the state of the art and future perspectives[J]. Angew Chem Int Ed, 2001, 40:486-516.
  • 3Filby M H, Steed J W. A modular approach to organic, coordination complex and polymer based podand hosts for anions[J]. Coord Chem Rev, 2006, 250: 3200-3218.
  • 4Sato K, Arai S, Yamagishi T, A new tripodal anion receptor with C(H^+ X^- hydrogen bonding[J].Tetrahedron Lett, 1999, 40.. 5219-5222.
  • 5Alcalde E, Mesquida N, P rez-Garc a L, et al. Hydrogen bonded driven anion binding by dicationic [14]imidazoliophanes [J]. Chem Commun, 1999, 295-296.
  • 6党东宾,柏.基于(C—H)^+…X^-氢键作用的阴离子识别与传感的研究进展[J].化学研究,2006,17(4):91-95. 被引量：2
  • 7Bai Y, Zhang B G, Xu J, et al. Conformational switching fluorescent chemosensor for chloride anion [J]. New J Chem, 2005, 29: 777-779.
  • 8Bai Y, Zhang B G, Duan C Y, et al. Anion induced binding electrochemical signal transduction in ferrocenyl benzolimidazolium podands [J]. New J Chem, 2006, 30: 266-271.
  • 9Kwon J Y, Singh N J, Kim H N, et al. Fluorescent GTP-sensing in aqueous solution of physiological pH [J]. J Am Chem Soc, 2004, 126: 8892-8893.
  • 10Yoon J, Kim S K, Singh N J, et al. Midazolium receptors for the recognition of anions [J]. Chem Soc Rev, 2006, 35: 355-360.

二级参考文献28

  • 1Beer P D, Gale P A. Anion recognition and sensing: the state of the art and future perspectives [ J ]. Angew Chem Int Ed, 2001,40: 486-516.
  • 2Park C H, Simmons H E. Macrobicyclic amines. Ⅲ. encapsulation of halide ions by in,in-1, ( k + 2) -diazabicyclo[ k. l. m. ] alkane ammonium ions [J]. J Am Chem Soc, 1968, 90:2431 -2432.
  • 3Abouderbala L O, Belcher W J, Boutelle M G, et al. Cooperative anion binding and electrochemical sensing by modular podands[J]. Proc Natl Acad Sci, USA. 2002, 99:5001 -5006.
  • 4Amendola V, Fabbrizzi L, Monzani E. A concave fluorescent sensor for anions based on 6-methoxy-1-methylquinolinium [ J].Chem Eur J, 2004, 10:76 -82.
  • 5Sato K, Arai S, Yamagishi T. A new tripodal anion receptor with C-H^+ X^- hydrogen bonding [ J ]. Tetrahedron Lett, 1999,40:5219-5222.
  • 6Thomas J, Howarth J, Hanlon K, et al. Ferrocenyl imidazolium salts as a new class of anion receptors with C-H^+ X^- hydrogenbonding [J]. Tetrahedron Lett, 2000, 41 : 413 -416.
  • 7Bai Y, Zhang B G, Xu J, et al. Conformational switching fluorescent chemosensor for chloride anion [ J]. New J Chem, 2005,29 : 777 - 779.
  • 8Bai Y, Zhang B G, Duan C Y, et al. Anion induced binding electrochemical signal transduction in ferrocenyl benzolimidazolium podands [J]. New J Chem, 2006, 30:266-271.
  • 9Ihm H, Yun S, Kim H G, et al. Tripodal nitro-imidazolium receptor for anion binding driven by (C-H)^+ X^- hydrogen bonds[J]. Org Lett, 2002, 4:2897-2900.
  • 10Yun S, lhm H, Kim H G, et al. Molecular recognition of fluoride anion: benzene-based tripodal imidazolium receptor [ J ]. J Org Chem, 2003, 68: 2467 -2470.

共引文献1

同被引文献11

引证文献1

河南大学学报（自然科学版）
2008年 第3期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部