摘要
The complex, Ni[(C_(13)H_7Br_2NOS)_2(DMF)]·(C_3H_7O) (DMF=N,N′-dimethylformamide), was synthesized and characterized by the element analysis, IR and X-ray diffraction single crystal structure determination. The title complex crystallizes in monoclinic system, space group P21/n, with a=8.297 6(15) nm, b=12.866(2) nm, c=31.889(3) nm, β=95.024(2)°, and V=3 391.3(9) nm^3, Z=4, R=0.075 2, wR=0.176 8. The nickel iron is six-coordinated by three O atoms, two N atoms, one S from the Schiff base and one O atom from DMF ligand, forming a octahedron coordination geometry. Schiff bases are bridged by the two S atoms. The molecules in the crystal are linked through intermolecular Br…Br, C-H…O, S…Br interactions. Its electrochemical property is reported.
The complex, Ni[（C13H7Br2NOS）2（DMF）]·（C3H7O） （DMF=N,N′-dimethylformamide）, was synthesized and characterized by the element analysis, IR and X-ray diffraction single crystal structure determination. The title complex crystallizes in monoclinic system, space group P21/n, with a=8.297 6（15） nm, b=12.866（2） nm, c=31.889（3） nm, β=95.024（2）°, and V=3 391.3（9） nm^3, Z=4, R=0.075 2, wR=0.176 8. The nickel iron is six-coordinated by three O atoms, two N atoms, one S from the Schiff base and one O atom from DMF ligand, forming a octahedron coordination geometry. Schiff bases are bridged by the two S atoms. The molecules in the crystal are linked through intermolecular Br…Br, C-H…O, S…Br interactions. Its electrochemical property is reported.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2008年第5期823-826,共4页
Chinese Journal of Inorganic Chemistry
基金
广西教育厅学科软环境建设基金资助项目(No.D200352)
关键词
席夫碱
镍(Ⅱ)配合物
晶体结构
电化学性质
热重分析
Schiff base
nickel（Ⅱ） complex
crystal structure
electrochemical measurements
thermal analysis
