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烯烃易位聚合研究新进展在合成嵌段共聚物及功能高分子上的应用 被引量:2

Recent Advances in Olefin Metathesis Polymerization: Application to Synthesis of Block Copolymer and Functional Polymer
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摘要 本文详述了利用环烯烃开环易位聚合合成AB、ABA和星形嵌段共聚物、接枝共聚物、氧化还原性聚合物、侧链液晶高分子、导电高分子及含金属纳米聚合物材料,并对其具体合成路线作了概述。 In this paper the methods of synthesizing AB or ABA type block copolymer,graft copolymer and functional polymer such as redox active polymer,side chain liquid crystal polymer,conducting polymer,metal containing polymer via living ring opening metathesis polymerization are reviewed,and their specific synthetic routs are also described.
出处 《高分子通报》 CAS CSCD 1997年第3期144-153,共10页 Polymer Bulletin
关键词 环烯烃 开环易位聚合 嵌段共聚物 易位聚合 ROMP Cyclo olefin Ring [KG9]opening Metathesis Polymerization,Catalyst,Block copolymer,Functional polymer
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  • 6Chauvin Y. Olefin metathesis: the early days (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3740-3747.
  • 7Schrock R R. Multiple metal–carbon bonds for catalytic metathesis reactions (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3748-3759.
  • 8Grubbs R H. Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture). Angew. Chem., Int. Ed., 2006, 45(23): 3760-3765.
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  • 10Tebbe F N, Parshall G W, Reddy G S. Olefin homologation with titanium methylene compounds. J. Am. Chem. Soc., 1978, 100 (11): 3611-3613.

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