高分子担载卟啉及其金属络合物研究进展

New Developments of Polymer-supported Porphyrins and Their Metallic Complexes

本文介绍了高分子担载卟啉及其金属络合物在模拟细胞色素Ｐ－４５０、光学灭菌材料、阴离子载体及光敏化材料等领域的最新研究进展。

Porphyrins and their metallic complexes have many particular properties ,and they have been widely used as models of cytochrome P-450,oxidation catalysts, chemical electrodes and special functional materials etc.. When supported with SiO 2 or montmorillonite or organic polymers,the porphyrins or their metallic complexes are compartmentalized ,and exhibit better oxidation resistance. This paper reviews the new developments of synthesis and properties of polymer-supported porphyrins and their metallic complexes,especially as models of cytochrome P-450,photobactericidal materials ,anion carriers,sensitization and electron transfer materials and so on.