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超临界CO_2技术在高分子科学中应用的研究进展 被引量:4

The applications of supercritical CO_2 in polymer science
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摘要 本文综述了超临界CO_2的特殊性质,如溶解能力和溶胀能力随压力急剧变化等,总结了它在高分子科学中的应用,包括以它为介质的溶液聚合、乳液聚合、分散聚合、沉淀聚合反应及RESS技术、分级技术等. This paper reviews 19 articals concerning Supercritical CO_2, including the following contents: 1. The characteristies of SC-CO_2 such as the dramatic dependence of its dissolving and swelling power on the pressure. 2. the applications of SC-CO_2 in poly-merzation such as solution,emultion, dispersion and precipetation polymerization in supercritical CO_2. 3. Polymer processing techniques by using SC-CO_2 including RESS,fractionation technique etc.
出处 《广州化学》 CAS 1997年第3期55-63,共9页 Guangzhou Chemistry
基金 国家自然科学基金
关键词 高分子科学 超临界二氧化碳 萃取剂 溶剂 supercritical CO_2 Polymer science, application
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参考文献1

  • 1Tibor Pernecker,Joseph P. Kennedy. Carbocationic polymerizations in supercritical carbon dioxide[J] 1994,Polymer Bulletin(5-6):537~543

同被引文献39

  • 1王轶,李志义,胡大鹏,刘学武,张晓冬,夏远景.超临界二氧化碳对聚合物的增塑作用及应用[J].化学工业与工程技术,2004,25(3):23-26. 被引量:18
  • 2田军,徐锦芬,潘光明,周兆福,薛群基.含氟的聚合物及其应用[J].功能高分子学报,1995,8(4):504-511. 被引量:28
  • 3曹现福,陈鸣才,陈德宏,王长安,许凯.超临界二氧化碳在高分子合成及加工领域的应用[J].高分子通报,2006(7):65-70. 被引量:11
  • 4王文贵,杨勇,陈秉倪.乙烯-三氟氯乙烯共聚物(ECTFE)的研究进展[J].有机氟工业,2007(2):28-32. 被引量:10
  • 5[1]Britto L J D,Soares J B P,Penlidis A.High-density polyethylene fractionation with supercritical propane[J].Journal of Polymer,Part B:Polymer Physics,1999,37:553-560.
  • 6[2]Iskender Yilgor,James E Mcgrath.Novel supercritical fluid techniques for plymer fractionation and purification[J].Polymer Bulletion,1984,12:499-506.
  • 7[3]Debjeet Pradhan,Chang-keng Chen,Maciej Radosz.Fractionation of polystyrene with supercritical propane and ethane:Characterization,semibatch solubility experiments,and SAFT simulations[J].Ind Eng Chem Res,1994,33:1 984.
  • 8[7]Maria-Dolores Bermudez,Francisco-Jose Carrion-Vilches.Supercritical carbon dioxide extraction of a liquid crystalline additive from polystyrene matrices[J].Journal of Supercritical Fluids,2002,23:59-63.
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