超微盘电极上同时受扩散、化学反应、电极反应速率控制的伏安统一理论

The Generalized Linear Voltammetric Theory of Quasi reversible Charge Transfer Coupled with Fist Order Homogenous Chemical Reaction at Ultramicrodisk Electrode

运用积分变换法推导了超微盘电极上同时受扩散、电化学反应、化学反应伏安法统一理论．对簿层电解池中超微盘电极伏安方程进行了研究，列出了计算所得的典型伏安曲线．

The theory of electrochemical processes coupled with homogenous first order chemical reaction occuring at ultramicrodisk electrode are investigated by means of integral transformations. Semi analytical solution relative to the EC, EC and CE coupled with quasireversible charge transfer are obtained. In addition, the equation of voltammogram at thin layer cell is studied. The voltammogram can be calculated by numerical method, and the typical theoretical i E curves are shown in this paper.