摘要
讨论了金属离子Ｍｎ（Ⅲ），Ｆｅ（Ⅲ），Ｒｈ（Ⅲ）和Ｐｄ（Ⅱ）原卟啉Ⅸ－二甲酯（ＰＰ）和四苯基卟啉（ＴＰＰ）配合物及Ｐｄ（Ⅱ）间氯四苯基卟啉（ＴＰＰｍ－ｃｌ）配合物的共振拉曼光谱。利用金属离子外层ｄ电子与卟啉环的作用，解释了配合物结构灵敏带的变化规律，同时讨论了不同卟啉及卟啉环上取代基团对结构灵敏带的影响。
The resonance Raman spectra of Mn(Ⅲ),Rh(Ⅲ),Fe(Ⅲ),Pd(Ⅱ) protoporphyrin Ⅸ dimethylester (PP) and tetra phenylporphyrin(TPP)complexes were reported.The difference of their structure sensitive band frequency was a result of the interaction of different metal ions′ outer d electrons with the electrons of the porphyrin ring.As well the effects of different porphyrin rings and their substituts on the structure sensitive bands were discussed in this paper.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1997年第5期40-44,共5页
Spectroscopy and Spectral Analysis
关键词
锰
铁
铑
钯
卟啉
配合物
共振拉曼光谱
Protoporphyrin Ⅸ dimethyl ester
Tetra phenyl porphyrin
Transition metal
Resonance Raman spectra
