摘要
在室温下由邻苯二甲酰亚胺[phthalimide,H(Pht)]与Cp_3Ln在四氢呋喃溶液中反应,合成了六个新化合物:Cp_2Ln(pht),CpLn(pht)_2,(Cp=cyclopentadienyl;Ln=Yb、Er、Dy;pht=phthalimldo)。它们均经元素分析、红外光谱和质谱鉴定,为非溶剂化的桥式二聚体结构。
Six new complexes of the general formulae, Cp2Ln(pht) and CpLn(pht)2, (Cp = Cyclopentadienyl, Ln = Yb, Er, Dy; pht = phthalimido) , have been synthesized. All the complexes were characterized by elemental analysis, IR and MS, showing that they are dimers with phthalimido as bridging groups.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1997年第3期277-280,共4页
Chinese Journal of Organic Chemistry
关键词
镧系化合物
邻苯二甲酰亚胺
环戊二烯
lanthanide complexes, phthalimide(P), cyclopentadiene(P),synthesis
