钍和铀酰的高氯酸盐与2,2'-二喹啉甲烷固体配合物的研究

SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF THORIUM,URANYL PERCHLO- RATES WITH BIS-QUINOLYLMETHYLENE

本文报道了钍、铀酰的高氯酸盐与2,2′-二喹啉甲烷(Biqm)的新型固体配合物Th(Biqm)_5(ClO_4)_4,UO_2(Biqm)_2(ClO_4)_2的合成,以及对该配合物所进行的元素分析、红外光谱、紫外光谱、差热-热重分析、荧光光谱、摩尔电导等方面的研究结果。

The solid complexes of thorium, uranyl perchlorates with bis-quinolylme-thylene (Biqm) having the composition Th(Biqm)5(ClO4)4, UO2(Biqm)2 (ClO4)2 have been synthesized in nonaqueous solvents.These two complexes have been characterized by elemental analysis, IR and UV spectra, differential thermal analysis (DTA) and thermogravimetry (TG) , fluorescence spectra and molar conductances.