超支化高分子的理论研究进展

Summarization of the Theoretical Studies on Hyperbranched Polymers

以ABb型缩聚反应体系为主从理论角度较为系统地对超支化高分子近年来的理论研究进行了总结,重点指出了统计力学、热力学、微分动力学方程、反应动力学和分子模拟等一些理论方法在相关研究中的应用.这些理论研究工作有助于更好地研究超支化高分子结构和性能的关系,为合成具有指定性能的超支化高分子提供了有意义的线索,从而可为全面研究超支化高分子的结构特征提供必要的支持.

The recent developments of theoretical studies on the hyperbranched polymer of ABb type are summarized in this paper. The theoretical methods are focused on the application of statistical mechanics, thermodynamics, kinetics and reaction dynamics and molecular modeling. These investigations are helpful to reveal the relation between the structures and properties of hyperbranched polymer, and can provide more clues for its synthesis. Correspondingly, these theoretical researches play an important role in studying the aggregated state of hyperbranched polymer in a deep level.