配位聚合物[Zn(C_7H_5N_2)_2]_n的合成和晶体结构

Synthsis and Crystal Structure of the Coordination Polymer [Zn(C_7H_5N_2)_2]_n

合成了[Zn(C7H5N2)2]n,并对其结构进行了表征,X射线单晶结构分析表明:晶体属单斜晶系,CC空间群.晶胞参数:a=8.039(4),b=8.043(4),c=19.725(11),V=1267.7(12)3,Dc=1.570 g/cm-3,Z=4,β=96.269(6)°,μ=1.927 mm-1,R1=0.086 9,wR2=0.217 7.

In this article, We synthesized the coordination polymer [Zn（C7H5N2）2]n, and characterised by X-ray diffraction, single crystal structure analysis shows that： [Zn（C7H5N2）2]n in monoclinic crystal systerm, Cc space group, a=8.039（4）A,b=8.043（4）A,c=19.725（11）A,V=1267.7（12）A^3,Dc=1.570 g/cm^-3,Z=4,β=96.269（6）°,μ=1.927 mm-^1,R1=0.086 9,wR2=0.217 7.