摘要
利用熔化相变的热力学、动力学参数,对Cu-Ti、Cu-Cr、Cu-Ti-O及Cu-Cr-O系合金建立物化工艺过程的平衡条件、多相系统的热力学、动力学参数与其热电性能之间的相互关系,以便了解这类合金的组织和性能,并用相关溶解模型(AssociatedSolutionModel-ASM)描述了这类二元液溶体的热力学性质.
With the thermodynamics and kinetics parameters of the melting processes, this papaer establishes the equilibrium conditions of the physical chemical processes in the system Cu Ti,Cu Cr,Cu Ti O,Cu Cr O,and the correlation between the thermodynamics and kinetics parameter and the thermal and electical properties of the heterogeneous systems,aiming at a better understanding of the sturcture and the properties of these alloys. The Associated solution Model(ASM) has been used to describe the thermodynamical properties of the binary liquid solution.