氯化铯和氯化镧溶剂体系及四类新化合物的合成

Studies on CsCl LaCl 3 HCl(HAc) H 2O Systems and New Ways of Synthesizing Complex Compounds

研究了四元体系ＣｓＣｌＬａＣｌ３ＨＣｌＨ２Ｏ（２５℃，［ＨＣｌ］＝１３％（ｗｔ），２３％（ｗｔ）和ＣｓＣｌＬａＣｌ３ＨＡｃＨ２Ｏ（３０℃，［ＨＡｃ］＝４２％（ｗｔ））的平衡态的溶度数据，并绘制了相应的溶度图，共得到了ＣｓＣｌ·ＬａＣｌ３·４Ｈ２Ｏ、２ＣｓＣｌ·ＬａＣｌ３·２Ｈ２Ｏ和３ＣｓＣｌ·ＬａＣｌ３·３Ｈ２Ｏ３种化合物。对得到的新相进行了热分析，Ｘ射线粉末衍射及偏光性质的测定。依据相化学关系对Ｍｅｙｅｒ反应的机理提出了新的解释，并设计了ＣｓＣｌ∶ＬａＣｌ３＝１∶２（２∶１，３∶２，３∶１）（摩尔比）的化合物的合成方法。

The solubilities of the saturated solution of quarternary system: CsCl LaCl 3 HCl H 2O(25 ℃, =13%(wt), 23%(wt) and CsCl LaCl 3 HAc H 2O(30 ℃, =42%(wt)) have been studied. The corresponding equilibrium diagrams were constructed. New compounds CsCl·LaCl 3·4H 2O, 2CsCl·LaCl 3·2H 2O, 3CsCl·LaCl 3·3H 2O were obtained from the equilibrium systems, and the X ray powder diffraction. TG DTG, DTA properties of the compoundes were studied respectively. The mechanisms of Meyer′s reactions were further interpreted. Based on the new compounds obtained from the equilibrium systems, new ways of synthesizing the compounds with: CsCl∶LaCl 3=1∶2, 2∶1, 3∶2, 3∶1 were designed.