聚合物键联铜卟啉的合成及其催化作用

The Synthesis of Polymer Bonded Copper Porphyrin Complexes and Its Oxidation Catalysis for Propanethiol

聚合物键联铜卟啉的合成及其催化作用１）蔡哲斌（湖北农学院应用化学系荆沙４３４１０３）张曼征（湖北省化学研究所武昌４３００７３）关键词卟啉铜络合物聚合物键联卟啉催化氧化丙硫醇卟啉及其金属络合物具有生物化学重要性［１］，并且是多用途的功能材料，广泛用于分...

p hydroxybenzyl) 10,15,20 tri(p methoxyphenyl)porphyrin(Ⅰ)and its copper complex (Ⅱ)were synthesized.Polymer bonded porphyrin(Ⅲ)was prepared by attaching functionalized compound(Ⅰ)to chloromethylated polystyrene resin via ether linkage.Polymer bonded copper porphyrin complex(Ⅳ)was then obtained by coordinating copper ion to the polymer bonded porphyrin compound(Ⅲ).Their chemical structures were identified by UV and IR spectra as well as elemental analysis.The catalytic activity of compound(Ⅳ) for the oxidation of propanethiol was studied.The composition of the products was also identified by HPLC,UV,IR and MS.