The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones

The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones

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摘要 One novel carbon-carbon bond insertion reaction of arynes has been developed. By this reaction β-keto sulfones can insert the triple bond of arynes to prepare polysubstituted ortho-keto benzyl sulfones. One novel carbon-carbon bond insertion reaction of arynes has been developed. By this reaction β-keto sulfones can insert the triple bond of arynes to prepare polysubstituted ortho-keto benzyl sulfones.

作者 Jian Xue Lu Ling Wu Xian Huang

机构地区 Department of Chemistry State Key Laboratory of Organometallic Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第6期631-633,共3页 中国化学快报（英文版）

基金 We are grateful to the National Natural Science Foundation of China （Nos. 20332060 and 2472072）

关键词 ARYNES Insertion reaction C-C bonds β-Keto sulfones arynes Insertion reaction C-C bonds β-Keto sulfones

分类号 O6 [理学—化学]

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1H.Yoshida,T.Minahe,J.Ohshita. Chemical Communications . 2004
2H.Yoshida,M.Watanahe,J.Ohshita. Chemical Communications . 2005
3D.Kumar,S.M.Swapna,G.Patel,V.S.Rao,R.S.Varma. Tetrahedron Letters . 2006
4.
5Z.Liu,R.C.Larock. Organic Letters . 2003
6Z.Liu.,R.C.Larock. Organic Letters . 2004
7H.Yoshida,T.Minabe.,J.Ohshita. Chemical Communications . 2005
8H.Yoshida.,M.Watanabe.,J.Ohshita. Chemistry Letters . 2005
9U.K.Tambar.,B.M.Stoltz. Journal of the American Chemical Society . 2005
10X.Creary. Accounts of Chemical Research . 1985

1Pei Qiang HUANG,Xiang Su,FEI and Hong ZHENG(Department of Chemistry, Xiamen University, Xiamen 361005).α-AMIDOALKYLATION　VIA　SULFONES:TOWARDS　THE　SYNTHESIS　OF　ANT　VENOM　ALKALOIDS[J].Chinese Chemical Letters,1995,6(9):739-742.
2Cai Ding XU Ji Qing JIANG Xian HUANG Department of Chemistry,Hangzhou University,Hangzhou 310028..A NEW SYNTHESIS OF SULFONES VIA THE ZINC—ASSISTED COUPLING OF ARENESULFONYL CHLORIDE WITH ALKYL HALIDES[J].Chinese Chemical Letters,1993,4(12):1051-1052.
3徐翠莲,王敏灿,侯学会,刘宏民,王德坤.Synthesis of New Chiral [2-（1-Hydroxyalkyl）pyrrolidino]methylferrocenes and Application to the Catalytic Asymmetric Addition of Diethylzinc to Arylaldehydes[J].Chinese Journal of Chemistry,2005,23(10):1443-1448. 被引量：1
4胡荣华,陈桂琴,蔡明中.A Novel Stereoselective Synthesis of （1Z,3E）-2-Phenyl（or p-Tolyl）sulfonyl-substituted 1,3-Dienes via Palladium Catalyzed Cross-coupling Reactions of （E）-α-lodovinyl Sulfones[J].Chinese Journal of Chemistry,2007,25(12):1927-1931.
5王小进,林云,刘金涛.Conjugate Additions of Secondary Amines and Water to Allenyl Perfluoroalkyl Sulfones[J].Chinese Journal of Chemistry,2006,24(6):775-780.
6ZHANG Zheng-hui SHI Wen-fang.Facile Route to Aromatic Hyperbranched Poly(ester amines)[J].Chemical Research in Chinese Universities,2009,25(3):400-403.
7Chuan Lu Wan Yong Ma Yu Zhen Fang Jian Hua Zhou.Theoretical studies of insertion reactions of singlet germylene into aryl C-C1 bond of 1-chlorobenzene[J].Chinese Chemical Letters,2009,20(3):374-377.
8ZHOU,Cheng-He BAI,Xue LI,Tan-Qing WU,Jun Alfred Hassner.Preparation and Reactions of Amino Acid Ester Sulfones as New Remote Asymmetrical Induced Reagents[J].有机化学,2004,24(z1).
9Lin He,Ji Xin Pian,Jing Zhang,Yuan Zhen Li.Highly efficient synthesis of 9-aminoxanthenes via the tandem reaction of arynes with salicyl N-tosylimines[J].Chinese Chemical Letters,2012,23(12):1359-1362. 被引量：2
10王小进,刘金涛.Unusual Cycloadducts from the Dipolar Cycloaddition of Allenyl Perfluoroalkyl Sulfones to Nitrones[J].Chinese Journal of Chemistry,2007,25(5):649-652.

Chinese Chemical Letters

2008年第6期

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The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones

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