控制卷积量变化的电化学方法研究——FeCl_3-H_2O_2体系催化性能的验证

Studies on Electrochemical Methods of Controlled Convolution —The catalytic process test of the system FeCl_3H_2O_2

控制卷积量变化的电化学实验方法是指将电流与时间的卷积作为可控制量的电化学实验方法，采用恒半积分法、半积分扫描法和半微分扫描法对氯化铁－双氧水体系进行了研究，获得了电极反应的扩散系数和标准电位值，并以循环伏安图和控制卷积量变化的电势～时间曲线证实了后续化学反应催化性能的存在。

The system FeCl_3H_2O_2 is studied in this paper by three kinds of controlled convolution elecrochemical experimental methods, which are constant semiintegral (CSI), linear semiintegral sweep(LSIS) and linear semidifferential sweep(LSDS). The diffusion coefficient D and the standard potential E0 of electron transfer reaction are obtained. According to the cyclic voltammogram and the E～t experimental curves of three controlled convolution methods, the catalytic process has been tested. The result is in good agreement with that previously reported.