摘要
采用萃取方法研究了Zn2+－bipy－PCA一体系中配体间的芳环堆积作用（bipy为2，2’-联吡啶，PCA-为苯基羧酸根），讨论了堆积百分率与配体中碳链长短及芳环大小的关系，合成并表征了混配配合物[Zn（bipy）（Bz）2]。
The stacking interactions of aromatic rings in the Zn2+-bipy-PCA- system (bipy = 2, 2'bipyridyl, PCA =phenylarboxylic acid) have been studied by extraction methods. The content of the stacked isomers increases in the order of Bz-<PAc-<PPr-<PBu-. The solid complex Zn(bipy) (Bz)2 has been synthesized and characterized by the elemental analysis, molar conductance, UV and IR spectroscopy, DTA and TG techniques.
出处
《浙江师大学报（自然科学版）》
1997年第4期59-61,共3页
Journal of Zhejiang Normal University(Natoral Sciences)
关键词
芳环堆积作用
锌
联吡啶
苯基羧酸
萃取
aromatic rings stacking interaction
zinc
2,2'-bipyridyl
phenylarboxylic acid
extraction
