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以天然可再生资源大豆油与CO2合成非异氰酸酯聚氨酯 被引量：10

Synthesis of non-isocyanate polyurethane using by the renewable resources soybean oil and carbon dioxide
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摘要 以天然可再生资源大豆油的环氧化产物(ESBO)和CO2为原料,四丁基溴化铵为催化剂,通过环加成反应合成大豆油五元环状碳酸酯(CSBO),考察了反应条件对该过程的影响,对产物进行了结构表征。然后用所合成的大豆油五元环状碳酸酯与脂肪族伯胺反应生成非异氰酸酯聚氨酯(NIPU),研究了不同环氧大豆油转化率对其成片机械性能的影响。 The synthesis of non-isocyanate polyurethane using by the renewable resources soybean oil and carbon dioxide under mild conditions in the presence of TBABr was presents. The structures of the Cyclic carbonates were characterized. Then cyclic carbonated Soybean oil react with primary aliphatic amine to prepare non-isocyanate polYurethane. The non-isocyanate polyurethane mechanical performances of different ESBO conversions were tested.
作者 李振荣 赵雨花 亢茂青 王军威 李其峰 王心葵 相宏伟
机构地区 中国科学院山西煤炭化学研究所
出处 《化工新型材料》 CAS CSCD 北大核心 2008年第6期37-38,63,共3页 New Chemical Materials
基金 中国科学院山西煤炭化学所创新基金项目(06SC531611) 山西省自然科学基金(青年基金)2007011036
关键词 可再生资源 大豆油 CO2 非异氰酸酯聚氨酯 renewable resource, soybean oil, carbon dioxide, non-isocyanate polyurethane
分类号 TQ323.8 [化学工程—合成树脂塑料工业]
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参考文献9

  • 1Figovsky O L, Shapovalov L, Axenov O. Advanced coatings based upon nonisocyanate polyurethanes for industrial applications[J]. Surf Coat Inter Part B: Coatings Transactions, 2004,87: 71-148.
  • 2Tomita H, Sanda F, Endo T. Structural Analysis of Polyhydroxyurethane Obtained by Polyaddition of Bifunctional FiveMembered Cyclic Carbonate and Diamine Based on the Model Reaction. [J]. J Poly Sci: Part A: Polymer Chemistry, 2001, 39: 851-859.
  • 3Tomita H, Sanda F, Endo T. Model Reaction for the Synthesis of Polyhydroxyurethanes from Cyclic Carbonates with Amines: Substituent Effect on the Reactivity and Selectivity of Ring-O- pening Direction in the Reaction of Five-Membered Cyclic Carbonates with Amine[J]. J Poly Sci: Part A: Polymer Chemistry, 2001, 39:3678-3685.
  • 4Lindblad M S, Liu Y, Albertsson A C, et al. Polymers from Renewable Resources[J]. Adv Poly Sci, 2002, 157: 139-161.
  • 5Mohanty A K, Misra M, Drzal L T. Sustainable Bio-Composires from Renewable Resources: Opportunities and Challenges in the Green Materials World [J]. J Poly Environ, 2002, 10: 19-26.
  • 6Tamami B, Sohn S, Wilkes G L. Incorporation of Carbon Dioxide into Soybean Oil and Subsequent Preparation and Studies of Nonisocyanate Polyurethane Networks [J]. J Appl Poly Sci, 2004, 92: 883-891.
  • 7Doll K M, Ethan S Z. The improved synthesis of carbonated soybean oil using supercritieal carbon dioxide at a reduced reaction time[J]. Green Chem, 2005, 7: 849-854.
  • 8Calo V, Nacci A, Monopoli A, Fanizzi A. Cyclic Carbonate Formation from Carbon Dioxide and Oxiranes in Tetrabutylammonium Halides as Solvents and Catalysts [J]. Org Lett, 2002, 4: 2561-2563.
  • 9Kim M R, Kim H S, Park D W, Lee J K. Synthesis of Cyclic Carbonates Based on Diglycidyl Ether of Bisphenols by Quaternary Armonium Salts[J]. React Kinet Catal Lett, 2001, 72: 373-381.

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化工新型材料
2008年 第6期

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