水中油浓度快速测量方法研究

Study on the Method for Rapid Determination of Oil Concentration in Water

以三维荧光光谱技术结合PARAFAC算法研究了水中油浓度的快速测量方法,重点分析了水中溶解有机物对油浓度测量的影响。以0#柴油、腐殖酸为测量样本,通过改变腐殖酸浓度来模拟自然水体中溶解有机物含量,研究了腐殖酸中0#柴油特征荧光光谱的快速分离方法,实现了不同腐殖酸浓度下相同浓度0#柴油含量的测量,测量平均误差为1.67%,相对标准偏差小于1.29%。结果表明,以三维荧光光谱技术结合PARAFAC算法能够实现水中大量溶解有机物存在下油浓度的快速测量。

The rapid determination of oil concentration in water was investigated with three dimensional fluorescence spectra and parallel factor analysis （PARAFAC）, and the influence of dissolved organic matter on the measurement of oil concentration was analyzed mainly. No. 0 diesel oil and humic acid was used for measuring sample in the experiment, the fast separation of No. 0 diesel oil fluorescence spectra from the overlapped spectrum of humic acid was studied through changing humic acid concentra- tion, the contents of No. 0 diesel oil was obtained under different humic acid simulation conditions, the maximum average error was 1.67%, and the relative standard deviation was less than 1.29%. The results showed the possibility of oil concentration fast determination with a variation of dissolved organic matter in water based on three dimensional fluorescence spectra technique and PARAFAC.