期刊文献+

气液界面对流传质的观测与定量分析 被引量:1

Quantitative Analysis and Observation of the Convection near Gas-Liquid Interface
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摘要 采用光学纹影系统对乙醇和水双组分解吸传质过程的对流结构的界面湍动进行了定性观察和定量分析。建立了一套水平非稳态气液传质设备,试验观测了乙醇和水体系中液相组分向气相传质过程的Marangoni界面对流结构。还通过对传统纹影方法的改进,对乙醇解吸传质过程的浓度(本文用质量分数表示)梯度场进行了定量测量。定量分析表明乙醇和水系统解吸过程中,引发界面湍动的原因是局部较大的表面张力梯度。定量分析的结果很好的解释了伴随Marangoni效应的传质过程的混乱的对流结构,为进一步对界面湍动现象的分析提供了帮助。 By utilizing the method of Schlieren system, interfacial turbulence of convective structure in desorption of ethanol from water was observed and quantitatively analyzed. Horizontal unstable gas-liquid mass transfer experimental equipment was set up. The Marangoni interfacial convective structures caused by gasliquid mass transfer in the interface during the desorption process of ethanol aqueous solution were observed. By employing the improved Schlieren, the concentration gradient of vicinity interface during gas-liquid mass transfer process was obtained. The quantitatively experimental result showed that the reason that induces the Marangoni convection is the local large surface tension gradient along the interface of the gas and liquid. This successfully explains the chaotic flow patterns obtained in gas-liquid mass transfer process accompanied by Marangoni effect and is helpful for the further study on the interfacial turbulence phenomena.
出处 《化学工业与工程》 CAS 2008年第4期283-288,309,共7页 Chemical Industry and Engineering
关键词 MARANGONI 气液传质 定量分析 纹影系统 Marangoni gas-liquid mass transfer quantitative analysis Schlieren system
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参考文献10

  • 1沙勇,成弘,袁希钢,刘春江,孙志发,余国琮.Optical Study on Concentration-Driven Rayleigh-Bénard-Marangoni Convection[J].Transactions of Tianjin University,2002,8(1):22-26. 被引量:2
  • 2ORELL A, WESTWATER J M. Spontaneous interfacial cellular convection accompanying mass transfer: Ethylene Glycol-Acetic Acid-Ethyl Acetate [J]. AIChE, 1962, 8 (3) : 350- 356.
  • 3IMAISHI N, FUJINAWA K. An optical study of interiacial turbulence accompanying chemical absorption [ J]. Intern Chem Engng, 1980, 20:226 - 232.
  • 4SUCIU D G, SMIGLSCHI O, RUCKENSTEIN E. Some experiments on the Marangoni effect [J]. AIChE, 1967, 13:1120-1124.
  • 5OKHOTSIMSKII A, HOZAWA M. Schlieren visualization of natural convection in binary gas-liquid systems [ J]. Chem Engng Sci, 1998, 53:2547-2573.
  • 6CHR BOYADJIEV. On the mechanism and kinetics of the transport processes in systems with intensive interphase mass transfer [J] . Int J Heat Mass Transfer, 2000, 53:2759 - 2766.
  • 7SUNZ F, YU K T, WANG S Y, MIAO Y Z. Absorption and desorption of carbon dioxide into and from organic solvents: Effects of Rayleigh and Marangoni instability [J]. Ind Eng Chem Res, 2002, 41:1905 - 1913.
  • 8ZHANG S H, WANG Z M, SU Y F. Mass transfer and interfacial turbulence in a laminar film/Study of transferring two solutes separately and simuhaneously through liquidliquid interlace [J]. Trans I Chem E, 1990, 68: 84- 92.
  • 9沙勇,成弘,袁希钢,余国琮,孙志发.双组分扩散过程Rayleigh-Bénard-Marangoni现象实验研究[J].化工学报,2002,53(9):976-979. 被引量:3
  • 10KLEINE S, VAN ENCKEVORT W J P, DERIX J. A dark field-type Schlieren microscope for quantitative, in situ mapping of solute concentration profiles around growing crystals [J]. Crystal Growth, 1997, 179: 240-248.

二级参考文献16

  • 1ImaishiN,FujinawaK. Intern.Chem.Engng . 1980
  • 2ZhangSH,WangZM,SuYF. Transactions of the Institution of Chemical Engineers . 1990
  • 3MatinAM,PerezAC. Intern.Chem.Engng . 1994
  • 4OkhotsimskiiA,HozawaM. Chemical Engineering Science . 1998
  • 5Sherwood T K,Pigford R L,Wilke C K.Mass Transfer[]..1975
  • 6Proctor S J,Biddulph M W,Krishnamurthy K R. American Institute of Chemical Engineers Journal . 1998
  • 7Zhang S H,Wang Z M,Su Y E.Mass transfer and interfacial turbulence in a laminar film/Study of transferring two solutes separately and simultaneously through liquid-liquid interface[].Transactions of the Institution of Chemical Engineers.1990
  • 8Lu H H,Yang Y M,Maa J R.Effect of artificially Provoked Marangoni convection at a gas/liquid interface on absorption[].Industrial and Engineering Chemistry Research.1996
  • 9Brian P L T,Ross J R.The effect of Gibbs adsorption on Marangoni instability in penetration mass transfer[].American Institute of Chemical Engineers Journal.1972
  • 10Guzun-Stoica A,Kurzeluk M,Floarea O.Experimental study of Marangoni effect in a liquid-liquid system[].Chemical Engineering Science.2000

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