摘要
A new metal-organic coordination polymer [Cd（5-hip）（phen）]n·nH2O 1 has been hydro- ermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The crystal of the complex crystallizes in monoclinic, space group P2/n with a = 8.8071（17）, b =12.386（2）, c = 16.981（3） A, β = 100.182（2）°, V = 1823.2（6） A^3, Mr=. 490.73, Dc =1.788 g/cm^3,μ（MoKa） = 1.240 mm^-1, F（000） = 976, Z= 4, the final R = 0.0458 and wR = 0.1373 for 2864 observed reflections （I 〉 2σ（I））. The Cd atoms are coordinated by two N atoms from the phen ligands and four O atoms from 5-hydroxyisophthalate ligands in a highly distorted octahedral geometry.
A new metal-organic coordination polymer [Cd（5-hip）（phen）]n·nH2O 1 has been hydro- ermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The crystal of the complex crystallizes in monoclinic, space group P2/n with a = 8.8071（17）, b =12.386（2）, c = 16.981（3） A, β = 100.182（2）°, V = 1823.2（6） A^3, Mr=. 490.73, Dc =1.788 g/cm^3,μ（MoKa） = 1.240 mm^-1, F（000） = 976, Z= 4, the final R = 0.0458 and wR = 0.1373 for 2864 observed reflections （I 〉 2σ（I））. The Cd atoms are coordinated by two N atoms from the phen ligands and four O atoms from 5-hydroxyisophthalate ligands in a highly distorted octahedral geometry.
