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4-苯甲酰氧基苯甲酸液晶性的研究 被引量:3

Studies on Liquid Crystallinity of 4-Benzoyloxybenzoic Acid
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摘要 ?The liquid crystallinity of the dimer of 4-benzoyloxybenzoic acid (BBA), with ex-cellent melt flow property was observed. The axial ratio (l/d) of (BBA), was calcu1ated tobe 5- 8 whlch is large en0ugh to exhlbit Iiquid crystalline phase. The nematic phase was sta-ble at 230 C. At higher temperature(270C ), the transesterification reaction occurred. Theeutectic temperature of BBA and 4-acetoxybenzoic acid is l75 C。 ?The liquid crystallinity of the dimer of 4-benzoyloxybenzoic acid (BBA), with ex-cellent melt flow property was observed. The axial ratio (l/d) of (BBA), was calcu1ated tobe 5- 8 whlch is large en0ugh to exhlbit Iiquid crystalline phase. The nematic phase was sta-ble at 230 C. At higher temperature(270C ), the transesterification reaction occurred. Theeutectic temperature of BBA and 4-acetoxybenzoic acid is l75 C。
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1997年第12期2070-2072,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金
关键词 苯甲酰氧基 苯甲酸 BBA 缔合物 液晶性 4-Benzoyloxybenzoic acid, 4-Acetoxybenzoic acid, 4-(4-Benzoyloxybenzoyloxy)benzoic acid, Dimer, Liquid crystallinity
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  • 1田颜清,高等学校化学学报,1995年,16卷,967页

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