摘要
聚甲基乙烯基酮的不对称还原反应李弘姚金水何炳林（吸附与分离功能高分子材料国家重点实验室南开大学高分子化学研究所天津３０００７１）关键词对称硅氢化，聚甲基乙烯基酮，手性噻唑烷，铑近年来手性过渡金属络合物催化的前手性酮和烯的不对称硅氢化反应已在国际上受...
Through the asymmetric reduction of poly(methyl vinyl ketone)and copolymer of mehtyl vinyl ketone and styrene, optical polymers with chiral alcohol groups were synthesized. The effect of measuring solvents on the specific rotatory power of the reduction products was investigated. It was found that the optical rotation was mainly caused by the chiral alcohol groups in the molecules of the synthesized polymeric alcohols.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
1997年第5期611-614,共4页
Acta Polymerica Sinica
基金
天津市自然科学基金
关键词
不对称
硅氢化
聚甲基乙烯基酮
铑催化剂
还原
Asymmetric hydrosilylation, Poly(methyl vinyl ketone), Chiral thiazolidine, Rhodium
