Ca2SiO4：Dy^3＋材料的制备及其发光特性

Preparation and luminescence characteristics of Ca_2SiO_4:Dy^(3+) phosphor

采用高温固相法制备了Ca2SiO4:Dy3+发光材料.在365nm紫外光激发下,测得Ca2SiO4:Dy3+材料的发射光谱为一多峰宽谱,主峰分别位于486nm,575nm和665nm处;监测575nm发射峰,测得材料的激发光谱为一多峰宽谱,主峰分别位于331nm,361nm,371nm,397nm,435nm,461nm和478nm处.研究了Dy3+掺杂浓度对Ca2SiO4:Dy3+材料发射光谱及发光强度的影响,结果显示,随Dy3+浓度的增大,黄、蓝发射峰强度比(Y/B)逐渐增大,利用Judd-Ofelt理论解释了其原因;随Dy3+浓度的增大,Ca2SiO4:Dy3+材料发光强度先增大,在Dy3+浓度为4mol%时到达峰值,而后减小,根据Dexter理论其浓度猝灭机理为电偶极-电偶极相互作用.研究了电荷补偿剂Li+,Na+和K+对Ca2SiO4:Dy3+材料发射光谱的影响,结果显示,不同电荷补偿剂下,随电荷补偿剂掺杂浓度的增大,Ca2SiO4:Dy3+材料发射光谱强度的演化趋势相同,即Ca2SiO4:Dy3+材料发射峰强度先增大后减小,但不同电荷补偿剂下,材料发射峰强度最大处对应的补偿剂浓度不同,对应Li+,Na+和K+时,浓度分别为4mol%,4mol%和3mol%.

The Ca2 SiO4 ：Dy3＋ phosphor was synthesized by high temperature solid-state method. The emission spectrum of Ca2 SiO4 ： Dy3＋ shows bands at 486 nm,575 nm and 665 nm under the 365 nm excitation. The excitation spectrum for 575 nm emission has excitation bands at 331 nm,361 nm,371 nm,397 nm,435 nm,461 nm and 478 nm. The effect of Dy3＋ concentration on the emission spectrum and luminescent intensity of Ca2 SiO4 ： Dy^3＋ was investigated. The result shows that the ratio （Y/B） of yellow emission （575 nm）to blue emission （486 nm）increases with increasing Dy^3＋ concentration, and the reason was explained by Judd-Offelt theory. The luminescent intensity firstly increases with the increasing Dy^3＋ concentration, then decreases, and the concentration self-quenching mechanisms are the d-d interaction according to the Dexter theory. The effect of Li^＋ , Na^＋ and K^＋ on the emission spectra of Ca2 SiO4 ： Dy^3 ＋ phosphor was studied. The results show that the emission spectrum intensity of Ca2 SiO4 ：Dy^3＋ phosphor is greatly influenced by Li^＋ , Na^＋ and K^＋ , and the evolvement trend is the same for different charge compensations, i. e., the emission spectrum intensity firstly increases with increasing charge compensation concentration, then decreases. However, the charge compensation concentration corresponding to the maximum emission intensity is different for different charge compensations,and the concentrations are 4,4 and 3 mol% for the Li^＋ ,Na^＋ and K^＋ ,respectively.