摘要
本文以普通型强碱性阴离子交换树脂作载体的铬(Ⅵ)试剂用于氧化苄醇、烯丙醇和仲醇类,取得了良好的效果,对饱和伯醇则不氧化。反应操作简单,树脂经再生后可循环使用。
This paper described the selective oxidations of benzylic,allylic and secondary alcohols to the correspondingcarbonyl compounds with 717 strong basic anion—exchange resin—supported chromium(Ⅵ)reagent in goodyield but unable to oxidize the saturated primary alcohols with it.Reaction procedure can be completed very readi-ly and the polymeric support can be regenerated without noticeable loss in reactivity.
出处
《河南师范大学学报（自然科学版）》
CAS
CSCD
1990年第2期98-100,共3页
Journal of Henan Normal University(Natural Science Edition)
基金
国家自然科学基金
关键词
有机化合物
选择性
氧化
铬
醇类
selective oxidation
polymer—supported chromium(Ⅵ)reagent
717 strong basic anion—exchange resin
