摘要
轴不稳定配体应用于不对称催化有其独到的特点,不同于传统的轴稳定手性配体.综述了轴不稳定的噁唑啉、双膦、单膦、双羟基及N—O等配体的开发及其在不对称催化中的应用.
Tropos ligands, compared with traditional atropos ligands, have unique characteristics. Here, the development of several major types of tropos ligands, including oxazoline, biphosphine, monophosphine, bihydroxyl and N--O ligands, and their applications to asymmetric catalysis are reviewed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2008年第7期1169-1180,共12页
Chinese Journal of Organic Chemistry
基金
高等学校博士学科点专项科研基金(No.20050248002)资助项目
关键词
轴手性
轴不稳定配体
不对称催化
axial chirality
axial-unfixed ligand
asymmetric catalysis