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金刚烷醚的便捷合成

Convenient Synthesis of Adamantyl Ethers
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摘要 溴代金刚烷和醇在Ag2S04作用下,方便地合成了一系列的金刚烷单醚(收率70.6%-96.0%)和金刚烷二醚(收率35.0%-64.0%),其结构经^1HNMR和”CNMR表征。 A series of adamantyl ethers were synthesized by the reaction of bromoadamantanes with alcohols in the presence of Ag2SO4. The yield of adamantyl monoethers and adamantyl diethers were 70.6% - 96.0% and 35.0% - 64.0%, respectively. The structures Were confirmed by ^1H NMR and ^13 C NMR.
出处 《合成化学》 CAS CSCD 2008年第4期467-469,471,共4页 Chinese Journal of Synthetic Chemistry
基金 浙江省科技计划资助项目(2006C31028)
关键词 金刚烷 合成 adamantane ether synthesis
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参考文献7

  • 1高治,苏晓明,王艳,井新利.金刚烷的应用开发[J].化工新型材料,2004,32(12):34-35. 被引量:9
  • 2Santiago A N, Toledo C A, Rossi R A. Reactions of halo- and dihaloadamantanes with nitromethane anions by the SRN 1 mechanism [ J ]. J Phys Org Chem, 2003, 16(8) :413 -419.
  • 3Moss R A, Tian J, Sauers R R. Solvent-equilibrated homoadamantyl chloride Ion pairs from chloroformate or oxachlorocarbene fragmentations [ J ]. Org Lett, 2004,6 (23) :4293 - 4296.
  • 4Miller J B, Salvador J R. Photoinduced electron-transfer substitution reactions via unusual charge-transfer intermediates[J]. J Org Chem,2002,67(2) :435-442.
  • 5Kevill D N, Kolwyck K C, Weitl F L. Correlation of solvolysis rates of 1-adamantyl p-toluenesulfonate [ J ]. J Am Chem Soc,1970,92(25) :7300 -7306.
  • 6胡晓春,孔黎春,冯云龙,吴利平.1,3-金刚烷二甲酸的制备[J].浙江师范大学学报(自然科学版),2004,27(2):152-154. 被引量:9
  • 7孔黎春,胡晓春.1,3-金刚烷二甲酸的气相色谱分析及组分鉴定[J].浙江师范大学学报(自然科学版),2006,29(2):164-166. 被引量:1

二级参考文献25

  • 1胡晓春,孔黎春,冯云龙,吴利平.1,3-金刚烷二甲酸的制备[J].浙江师范大学学报(自然科学版),2004,27(2):152-154. 被引量:9
  • 2[3]Kurt Baum,Pasadena,Archibald,et al.1,3-Diethynyladamantane and Methods of Polymerization Thereof [P].US:4849565,1989.
  • 3[4]石川,克宏.Diallyl adamantanedicarboxylate[P].Jap:60100537,1985.
  • 4[5]Ana N Santiago,Carlos A Toledo,Roberto A Rossi.Reactions of halo-and dihaloadamantanes with nitromethane anions by the SRN1mechanism[J].J Phys Org Chem,2003,16(8):413-419.
  • 5Kurt Baum, Pasadena, Archibald, et al. 1,3-Diethynyladamantane and Methods of Polymerization Thereof:US, 4849565 [P]. 1989- 07-18.
  • 6Sasaki Tadashi. Preparation of 1,3-Diisocyanteadamantane:Jap, 54046762[P]. 1979-04-12.
  • 7Ban Tetsuo, Yoshisato Akinobu, Muromoto Masaharu, et al. Methodfor producing adamantanedicarboxylic acid diaryl ester: Jap,2003252830[P]. 2003-09-10.
  • 8McHattie J S, Koros W J, Paul D R. [J]. Ploymor, 1991,32: 840
  • 9McHattie J S, Koros W J, Paul D R. [J]. Ploymor, 1992,33: 1701
  • 10Pixton M R,Paul D R.[J].Polymor,1995, 36:3165

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