摘要
合成了邻啰菲啉(Phen)-对苯二甲酸(p-Phtha)铜(Ⅱ)的混配配合物并获得晶体。X-射线单晶衍射、红外光谱分析表明该配合物组成为[Cu(Phen)2(p-Phtha)].5H2O,晶体属单斜晶系,C2/C空间群,晶胞参数为:a=11.623(7),b=32.51(2),c=16.341(10),β=95.022(9)°,V=6 150(7)3。Cu(Ⅱ)采取5配位方式,处于一个变形的四方锥配位环境中。
The title complex was synthesized by phenanthroline, terephthalic acid and copper monohydrate and characterized by X-ray diffraction and infrared spectrometry. The results showed that the composition of complex was [ Cu （Phen） 2 （ p-Phtha ） ] · 5H2O with a monoclinic crystal system comprising the space group C2/C with α = 11.623（7）A, b = 32.51 （2）A, c = 16.341 （ 10）A,β= 95.022（9）°,and V= 6 150（7）A^3.The copper（Ⅰ） ion has square pyramidal environment with five-coordinated configuration.
出处
《化学试剂》
CAS
CSCD
北大核心
2008年第8期591-593,616,共4页
Chemical Reagents
基金
山东省教育厅科技发展计划(J07WC03)
