期刊文献+

分散聚合研究进展及单分散聚合物微球的应用 被引量:3

Development of dispersion polymerization and the application of monodisperse polymer microspheres
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摘要 分散聚合是一种能得到很好单分散聚合物微球的新型聚合方法,该方法已广泛应用于医学、涂料工业、生物工程、化学工业等方面。大粒径单分散聚合物微球在许多领域里有着广阔的应用前景,越来越受到人们的关注。笔者对分散聚合中的反应机理、粒径的控制以及稳定剂和分散介质的研究进展进行了概述,并简要介绍了单分散聚合物微球的应用。 Dispersion polymerization is an attractive method for producing micron-size monodisperse polymer microsheres in a single batch. It has been applied in many fields, such as coating, bioengineering, medicine, chemistry industry etc. Micron-sized monodisperse polymer microspheres have been used in many fields and become a focus in resent years. The reaction mechanism and particle size control in dispersion polymerization were reviewed, stabilizer and medium in the polymerization process were introduced. And the application of micron-sized monodisperse polymer microspheres were simply discussed in this paper.
出处 《合成技术及应用》 2008年第2期25-30,共6页 Synthetic Technology & Application
基金 湖北省科技厅创新团队基金
关键词 分散聚合 单分散 超临界态二氧化碳 聚合物微球 dispersion polymerization monodisperse the supercritical carbon dioxide polymer microsphere.
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参考文献48

  • 1Dullens R P A, Claesson E M, Kegel W K. Preparation and properties of cross-linked fluorescent poly ( methyl methacryiate) latex coltoids[J]. Langmuir, 2004,20: 658 - 664
  • 2Kawaguchi H. Functional polymer microspheres[J]. Progress in polymer science, 2000,25:1171 - 1210
  • 3Santos R M, Forcada J. Acetal functionalized polymer particles useful for immunoassays[ J]. J Polym Sci A:Polym Chem, 1997,35:1605-1610
  • 4Vanderhoff J W, Brandford E B. Polymer colloid I(Fitch R M Ed). New York: Plenum Press, 1971
  • 5Mi S K, Gyu H L, Jae-Min H, et al. Synthesis of monodisperse PS-co- PDMS microspheres by dispersion polymerization [J]. Materials Science and Engineering, 2007,27 : 1247- 1251
  • 6Kyoung S O, Won B, Hwayong K. Dispersion polymerization of N - vinylcarbazole using siloxane-based and fluorine-based surfactants in compressed liquid dimethyl ether[J]. Polym, 2007(48):1450 -1454
  • 7Miraballes M I, Forcada J. Synthesis of latex particles with surface amino groups[J].J Polym Sci A: Polym Chem, 2000,38:4230-4237
  • 8Groucher M D, Winnlk M A. Futrue Dir Polymer Colloid[M]. 1987
  • 9Kawaguchi S, Ito K. Dispersion polymerization [J].Adv Polym Sci, 2005,175 : 299 - 328
  • 10Dai Q, Wu D Z, Zhang Z C, et al. Preparation of monodisperse poly (methyl methacrylate)particles by radiation-induced dispersion polymerization using vinyl terminus polysiloxane stabilizer[J]. Polym, 2003,44:73 -77

二级参考文献25

  • 1曹同玉,戴兵,戴俊燕.单分散大粒径聚合物微球的合成及应用[J].高分子通报,1995(3):174-180. 被引量:42
  • 2曹同玉,戴兵,戴俊燕,王艳君,袁才登.单分散、大粒径聚苯乙烯微球的制备[J].高分子学报,1997,7(2):158-165. 被引量:57
  • 3Chen G H,Nature,1995年,373卷,49页
  • 4Soppirnath K S, Tejraj M,et al. Eur. J. Pharm. Bioph., 2002, 53: 87.
  • 5Slomkawski S, Basinska T, Miksa B. Polym. Adv. Technol., 2002, 13: 905.
  • 6Covolan V L, Volpe P L O, de Castro S G C. Macromol. Chem. Phys., 2002, 203: 1454.
  • 7Correa R, Gonzalez G, Dougar V. Polymer, 1998, 39: 1471.
  • 8Zhu X L, Zhou N C, He X M,et al. J. Appl. Polym. Sci., 2003, 88: 1787.[7]Cheng Z P, Zhu X L, Chen G J,et al. J. Polm. Sci., Part A: Polym. Chem., 2002, 40: 3823.
  • 9Cheng Z P, Zhu X L, Chen G J,et al. J. Polm. Sci., Part A: Polym. Chem., 2002, 40: 3823.
  • 10Cao K, Li B G, Pan Z R. Colloids Surf. A: Physicochem. Eng. Aspects., 1999, 153: 179.

共引文献43

同被引文献27

  • 1单国荣,曹志海,黄志明,翁志学.聚丙烯酰胺-聚乙二醇-水体系相图及丙烯酰胺单体在两相中的分配[J].高等学校化学学报,2005,26(7):1348-1351. 被引量:21
  • 2施尔畏,夏长泰,王步国,仲维卓.水热法的应用与发展[J].无机材料学报,1996,11(2):193-206. 被引量:285
  • 3伍绍贵,刘白玲.分散聚合法制备微米级PMMA微球的研究[J].中国科学院研究生院学报,2006,23(3):323-330. 被引量:7
  • 4郭睿威,张建华,赵宗峰,戚桂村.N-咔唑二硫代甲酸异丙苯酯的合成及应用[J].天津大学学报,2007,40(8):906-910. 被引量:6
  • 5Zheng Q,Zheng G,Pan C. Preparation of nano-sizedpoly(ethylene oxide)star microgels via reversible addi tion-fragmentation transfer polymerization in selectivesolvents [J]. Polymer International,2006,55(9):1114-1123.
  • 6Huang C Q,Pan C Y. Direct preparation of vesiclesfrom one-pot RAFT dispersion polymerization[J]. Polymer,2010,51(22):5115-5121.
  • 7Wan W M,Pan C Y. One-pot synthesis of polymericnanomaterials via RAFT dispersion polymerization inducedself-assembly and re-organization[J]. PolymerChemistry,2010,1(9):1475-1484.
  • 8He W D,Sun X L,Wan W M,et al. Multiple morphologiesof PAA-b-PSt assemblies throughout RAFTdispersion polymerization of styrene with PAA macro-CTA[J]. Macromolecules,2011,44(9):3358-3365.
  • 9Bathfield M , D'Agosto F , Spitz R , et al. Submicrometersized hairy latex particles synthesized by dispersionpolymerization using hydrophilic macromolecularRAFT agents[J]. Macromolecular Rapid Communications,2007,28(15):1540-1545.
  • 10Oh J K. Recent advances in controlled/living radical polymerizationin emulsion and dispersion[J]. PolymerScience Part A:Polymer Chemistry,2008,46(21):6983-7001.

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