摘要
对EOW制备工艺中离子膜类型、电解方式和碱性水回流3个方面进行了考察,发现利用均相阴离子交换膜代替均相阳离子交换膜,可以有效地提高电解效率,原因在于阴离子膜可以有效地阻止H^+的反渗透;采用阴、阳电解槽同时加入电解质溶液并采用阴离子膜的电解方式最优;当回流比在40%~60%时可以得到合格的EOW,回流比为80%时得到EOW的pH值超出范围;回流比对EOW的ORP值和ACC值影响不大。设计了EOW制备的新工艺,提高了制备效率和电极使用寿命,减少了碱性水的排放。
The effects of ion membrane types, the electrolyticways and electrolyzed reductive water' s(ERW) reflux on the preparation technology of electrolyzed oxidizing water(EOW) are investigated. The results show that:(1)the electrolyticefficiency can be enhanced using anion exchange membrane instead of cation exchange membrane because the former one can effectively prevent hydrogen ion from permeating into cation cell; (2)the best way of electrolytic is that both cells are electrolytic solution and anion exchange membrane is used; (3)the eligible EOW can be obtained under the reflux ratio of 40% - 60%, and the value of pH will be out of range when the reflux ratio is above 80%. The effects of different reflux ratio on the value of oxidation reductive potential(ORP) and available chlorine content(ACC) are very little. A new preparing process is designed, which can not only enhance electrolytic efficiency and electrode lifetime, but also can decrease ERW discharge.
出处
《现代化工》
CAS
CSCD
北大核心
2008年第8期46-48,50,共4页
Modern Chemical Industry
基金
湖北省自然科学基金项目(2007ABA279)
武汉市中小企业创新基金[2006(69号)]
关键词
酸性氧化电位水
离子膜
电解方式
碱性水
回流比
electrolyzed oxidizing water
ion membrane
electrolytic manner
electrolyzed reductive water
reflux ratio