摘要
A zinc(Ⅱ) complex [(5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.040 7(5) nm, b=1.382 1(7) nm, c=2.435 1(13) nm, V=3.503(3) nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226.
A zinc（Ⅱ） complex [（5-（4-nitrophenyl）tetrazolato）2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.0407（5） nm, b=1.382 1（7） nm, c=2.435 1（13） nm, V=3.503（3） nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC： 684226.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2008年第8期1347-1351,共5页
Chinese Journal of Inorganic Chemistry
基金
东南大学启动基金资助项目
关键词
锌配合物:水热合成
晶体结构
荧光性质
zinc complex
hydrothermal synthesis
crystal structure
fluorescence
