碳酸二甲酯胺解合成氨基甲酸酯催化剂研究进展

Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate

对包括均相、多相和其他类型的碳酸二甲酯胺解合成氨基甲酸酯用的催化剂进行了综述,讨论了不同类型催化剂的特点,并对新型催化剂的开发进行了展望,指出高效、高选择性、经济环保且可重复利用的多相催化剂更具应用前景。

The catalysts for ammonolysis of dimethyl carbonate （DMC） to carbamates, including homogeneous catalysts, hetero-geneous catalysts and the others, were reviewed, and the characteristics of various catalysts were discussed. The future development of new type catalysts was forecasted, and it was pointed that the high efficient, selective, low cost, environment friendly and reusable heterogeneous catalysts will be more attractive for this reaction.