镉-二茂铁亚甲基苯并咪唑配合物的合成、晶体结构与电化学性质

Synthesis,Crystal Structure and Electrochemical Properties of Ferrocenyl Methyl Benzimidazole Cadmium Complex

制备了一个新型的三维超分子化合物:镉-二茂铁亚甲基苯并咪唑配合物[Cd(FB IM)2I2](FB IM=二茂铁亚甲基苯并咪唑),并通过X-射线衍射仪对其晶体结构进行了表征。循环伏安测试结果表明其氧化还原过程是受扩散控制的,计时电流法和计时电量法测得其扩散系数分别为1.02×10-5和1.36×10-5cm2/s。

A novel 3 - D superamolecular network [ Cd（FBIM）2I2 ] 1 （FBIM = ferrocenyl methyl benzimidazole） has been synthesized and structurally characterized by x - ray single crystal diffraction. The cyclic vohammetry （CV） studies show that the redox processes of 1 is controlled by the diffusion. The diffusion coefficients （D） are obtained from chronocoulometry （CC） and chronoamperometry （CA） methods. The D values are 1.02×10^-5 and 1.36 × 10^-5 cm^2/s, respectively.