期刊文献+

用MOCVD方法制备ZnO:B透明导电薄膜及其性能优化 被引量:3

CHARACTERISTICS AND GROWTH OF ZnO:B THIN FILMS BY MOCVD PROCESS
下载PDF
导出
摘要 采用金属氧化物化学气相沉积(MOCVD)方法在石英衬底上生长氧化锌(ZnO)薄膜。改变薄膜材料的生长温度和掺杂气体硼烷(B_2H_6)的流速,制备一系列薄膜样品。通过X-射线衍射(XRD)、扫描电子显微镜(SEM)、透过率、反射率、电阻率和原子力显微镜(AFM)等测试分析,研究了材料生长温度和B_2H_6流速对薄膜生长速度、微观结构、薄膜晶向、光学透过率、光学禁带宽度、电阻率、表面粗糙度等特征参量的影响,经过优化实验条件,获得薄膜电阻率在10^(-3)Ω·cm量级,可见光区域光学透过率在85%以上,成功制备低电阻率高光学透过率的ZnO透明导电薄膜。 Boron-doped ZnO thin films were deposited on the fused silicon substrates by MOCVD system in this work. The samples were fabricated with various growth temperatures and various flow rates of BE I-I6. Based on the measurement of XRD, SEM, AFM, Hall Effect, and optical transmittance and reflectivity, the characteristics of the thin films, including the crystal plane, optical transmittance, optical band gap energy, resistivity, roughness, were investigated. As a result of optimizing the experimental parameters, the electrical resistivity of n-ZnO: B film is about 10^-3Ω·cm , and the average optical transmittance in the visible light region is over 85%. Thus the transmittance conductive oxide (TCO) of ZnO :B with low resistivity and high transmittance was successfully obtained by MOCVD in this work.
出处 《太阳能学报》 EI CAS CSCD 北大核心 2008年第8期939-943,共5页 Acta Energiae Solaris Sinica
关键词 ZnO:B 光学透过率 电阻率 透明导电薄膜(TCO) MOCVD ZnO: B optical transmittance resisitivity transmittance conducitive oxide(TCO)film MOCVD
  • 相关文献

参考文献10

  • 1Nunes P, Fortunato E, Martins R. Influence of the post-treatment on the properties of ZnO thin films [ J ]. Thin Solid Films, 2001, 383(1) :277--280.
  • 2李微,孙云,何青,刘芳芳,李凤岩.孪生对靶直流磁控溅射制备ZnO:Al薄膜及其特性研究[J].人工晶体学报,2006,35(4):761-764. 被引量:10
  • 3Kwang Joo Kim, Young Ran Park. large and abrupt optical band gap variation in In-doped ZnO[J]. Appl Phys Lett, 2001, 78(4) :475.
  • 4Suzuki A, Matsushita T, Wada N, et al. Transparent conducting Al-doped ZnO films prepared by pulsed laser deposition[J]. Jpn J Appl Phys, Part 2, 1996, 35:L56.
  • 5Tsukazaki A, Saito H, Tamura K, et al. Systematic examination of cartier polarity in composition spread ZnO thin films codoped with Ga and N[J]. Appl Phys Lett, 21302, 81:235.
  • 6Kim K K, Kim H S, Hwang D K, et al. P-type ZnO thin films via phosphorus doping and thermal activation of the dopant[J]. Appl Plays Lett, 2003, 83:63.
  • 7Yoshino K, Fukushima T, Yoneta M. Structural, optical and electrical characterization on ZnO film grown by a spray pyrolysis method [J]. Journal of Materials Science : Materials in Electronics, 2005, 16:403--408.
  • 8Lucio-Lopez M A, Luna-Arias M A, Maldonado A, et al.Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray[ J]. Solar Energy Materials and Solar Cells, 2006, 90:733--741.
  • 9Mahalingam T, John V S, Raja M, et al. Electrodeposition and characterization of transparent ZnO thin films[J]. Solar Energy Materials and Solar Cells, 2005, 88 : 227--235.
  • 10Fay S, Kroll U, Bucher C, et al. Low pressure chemical vapour deposition of ZnO layers for thin-film solar cells: temperature-induced morphological changes [ J ]. Solar Energy Materials and Solar Cells, 2005,86: 385--397.

二级参考文献11

  • 1Ramanathan K,Teeter G,Keane J C,Noufi R.Properties of High-efficiency CuInGaSe2 Thin Film Solar Cells[J].Thin Solid Films,2005,480-481:499-502.
  • 2Kannan Ramanathan,Miguel A Contreras,et al.Properties of 19-2% Efficiency ZnO/CdS/CuInGaSe2 Thin-film Solar Cells[J].Prog.Photovolt:Res.Appl.2003,11:225-230.
  • 3Neelkanth G Dhere,Vivek S Gade,et al.Development of CIGS2 Thin Film Solar Cells[J].Materials Science and Engineering B,2005,116:303-309.
  • 4Walter Water,Chu Sheng-yuan.Physical and Structural Properties of ZnO Sputtered Films[J].Materials Letters,2002,55:67-72.
  • 5Minami T,Oohashi K,Takata S,et al.Preparations of ZnO∶Al Transparent Conducting Films by DC Magnetron Sputtering[J].Thin Solid Films,1990,193:721.
  • 6Shimomura T,Kim D,Nakayama M.Optical Properties of High-quality ZnO Thin Films Grown by a Sputtering Method[J].Journal of Luminescence.2005,112:191-195.
  • 7Hao Xiaotao,Ma Jin,Zhang Deheng,et al.Thickness Dependence of Structural,Optical and Electrical Properties of ZnO∶Al films prepared on Flexible Substrates[J].Appl.Surf.Sci.,2001,183:137.
  • 8Minami T,Nanto H,Shooh S,et al.The Stability of Zinc Oxide Transparent Electrodes Fabricated by RF Magnetron Sputtering[J].Thin Solid Films,1984,111:167.
  • 9Stringer J.Stress Generation and Relief in Growing Oxide Films[J].Corrosion Scieuce,1970,10:513-543.
  • 10Puchert M K,Timbrell P Y,Lamb R N.Post Deposition Annealing of Radio Frequency Magnetron Sputtered ZnO Films[J],J.Vac.Sci.Technol.1996,A14:2220-2230.

共引文献9

同被引文献51

  • 1Suzuki A, Matsnshita T, Wada N, et al. Transparent conducting Al-doped ZnO films prepared by pulsed laser deposition(Part2)[J]. Jpn J Appl Phys, 1996, 35: L56-L60.
  • 2Yoshino K, Fukushima T, Yoneta M. Structural, optical and electrical characterization on ZnO film grown by a spray pyrolysis method [ J ]. Journal of Materials Science: Materials in Electronics, 2005, 16: 403--408.
  • 3Lucio-Lopez M A, Luna-Arias M A, Maldonado A, et al. Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray [ J ]. Solar Energy Materials and Solar Cells, 2006, 90: 733--741.
  • 4Mahalingam T, John V S, Raja M, et al. Electrodeposition and characterization of transparent ZnO thin films[ J]. Solar Energy Materials and Solar Cells, 2005, 88: 227--235.
  • 5Look D C, Reynolds D C, Sizelove J R, et al. Electrical properties of bulk ZnO [ J]. Solid State Communications, 1998, 105: 399--401.
  • 6Li Wei, Sun Yun, Wang Yaxin, et al. Effects of substrate temperature on the properties of facing-target sputtered Aldoped ZnO thin films [ J]. Solar Energy Materials and Solar Cells, 2007, 91: 659---663.
  • 7Wenas W W,Yamada A,Takahashi K et al.Electricaland optical properties of boron-doped ZnO thin filmsfor solar cells grown by metalorganic chemical vapordeposition[J].J Appl Phys,1991,70:7119.
  • 8Yoshino M,Wenas W W,Yamada A et al.Large-areaZnO thin films for solar cells prepared byphoto-induced metal organic chemical vapor deposition[J].Jpn J Appl Phys,1993,32:726.
  • 9S.Fa¨y.Low pressure chemical vapour deposition ofZnO layers for thin-film solar cells[J].Solar EnergyMaterials&Solar Cells,2005,86:385-397.
  • 10S.Fa¨y.Opto-electronic properties of rough LP-CVDZnO:B for use as TCO in thin film silicon solar cells[J].Thin Solid Films,2007,515:8558-8561.

引证文献3

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部