HPMBP缩对氟苄胺合Ni(Ⅱ)配合物的合成、表征和量化计算

Synthesis,characterization and quantum chemistry caculation of the complex Ni(PMBP-p-fluorobenzylamine)_2

合成1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5(HPMBP)缩对氟苄胺席夫碱合Ni(Ⅱ)配合物,用红外、紫外光谱及元素分析进行结构表征,并对其进行了量子化学计算.结果表明,参与配位的N、O原子具有很强的接受和转移电子的能力,此配合物的活性部位主要是芳香环.

A nickel（Ⅱ） complex with the ligand derived from 1-phenyl-3-methyl-4-benzoyl-5-pyrazoylone and p-fluorobenzylamine was synthesized and characterized by elemental analysis,IR and UV spectra.The results of the quantum chemistry calculation of the complex indicated that the electrons of nitrogen atoms and oxygen atoms had strong capability of accepting and transferring the electrons,the active part of the complex mostly was the aromatic ring.