丙腈取代四氮杂大环配体及其配合物的合成与表征

SYNTHESIS AND CHARACTERIZATION OF 5,12 DIPHENYL 7,14 DIMETHYL 1,4,8,11 TETRAAZACYCLOTETRADECANE N,N′,N″,N TETRAETHYLCYANIDE AND ITS Cu(Ⅱ),Ni(Ⅱ)COMPLEXES

合成了５，１２—二苯基—７，１４—二甲基—１，４，８，１１—四氮杂环＋四烷—Ｎ，Ｎ′，Ｎ″，Ｎ—四（３—丙腈）及其Ｃｕ（Ⅱ）和Ｎｉ（Ⅱ）配合物，并对它们进行了元素分析及ＩＲ、′ＨＮＭＲ、ＵＶ—Ｖｉｓ和电导测定等表征。

A new ligand 5,12 diphenyl 7,14 dimethyl 1,4,8,11 tetraazacyclote tradecane N,N′,N″,N tetraethylcyanide and its Cu(Ⅱ),Ni(Ⅱ) complexes were synthesized and characterized by elemental analysis, IR, ′H NMR,UV Vis spectra and conductivity measurements.