摘要
本文合成了６种Ｎ－芳基取代苄胺．以四种苯并三氮唑Ｎ－Ｍａｎｎｉｃｈ碱分别与格氏试剂（正丁基溴化镁，苯基溴化镁）通过亲核取代反应，合成了产率满意的新的６种Ｎ－芳基取代苄胺（芳基：邻甲苯基，对甲苯基，间硝基苯基，对硝基苯基）．它们的结构经ＩＲ、１ＨＮＭＲ和元素分析确证．
Six N aryl substituted benzylamines have been synthesized through the nucleophilic substitution of four benzotriazoly N Mannich base (N o methylphenyl 1 benzotriazolylbenzylamine, N p methylphenyl 1 benzotriazoly 1 benzylamine, N m nitrophenyl 1 benzotriazolylbenzylamine, N p nitrophenyl 1 benzotriazolylbenzylamine) respectively with Grignard reagent (n C 4H 9MgBr or PhMgBr) in satisfactory yield. The structures of these new compounds have been IR, 1 HNMR and elemental analysis.
