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糖醇催化氢解制低级多元醇技术研究进展 被引量：1

Technology and Research Development of Hydrogenolysis of Sugar Alcohols to Lower Polyhydric Alcohols
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摘要 从总体流程、反应器类型、催化剂种类、分离方法和特点几方面总结了糖醇催化氢解为低级多元醇的工艺技术研究国内外现状,并对该工艺的研究方向作一展望。 Current state of hydrogenolysis of sugar alcohols to lower polyhydric alcohols is summarized from process flow, reactor types, catalysts, and separation methods and characters. The research prospect of this process is quite promising.
作者 范丹丹 黎元生
机构地区 抚顺石油化工研究院
出处 《当代化工》 CAS 2008年第4期403-405,434,共4页 Contemporary Chemical Industry
关键词 糖醇 氢解 多元醇 文献综述 Sugar alcohol Hydrogenolysis Polyhydric alcohol Review
分类号 TQ223.16 [化学工程—有机化工]
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参考文献24

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同被引文献42

  • 1沈宜泓,王帅,罗琛,刘海超.生物质利用新途径:多元醇催化合成可再生燃料和化学品[J].化学进展,2007,19(2):431-436. 被引量：21
  • 2Bozell J J, Petersen G R. Technology development for the production of biobased products from biorefinery carbohydrates - the US department of energy's "top 10" revisited [J]. Green Chemistry, 2010, 12: 539-554.
  • 3Huber G W, Iborra S, Corma A. Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering. [J].Chemical Reviews, 2006, 106: 4044-4098.
  • 4Ruppert A M, Weinberg K, Palkovits R. Hydrogenolysis goes bio: from carbohydrates and sugar alcohols to platform chemicals[J]. Angewandte Chemie International Edition, 2012, 51: 2564 -2601.
  • 5Sohounloue D K, Montassier C, Barbier J. Catalytic hydrogenolysis of sorbitol[J]. Reaction Kinetics and Catalysis Letters, 1983, 22 (3-4): 391-397.
  • 6Andrews M A, Klaeren S A. Selective hydrocracking of monosaccharide carbon-carbon single bonds under mild conditions. Ruthenium hydride-catalyzed formation of glycols[J].Journal of the American Chemical Society, 1989, 111 (11): 4131-4133.
  • 7Montassier C, Giraud D, Barbier J. Polyol conversion by liquid phase heterogeneous catalysis over metals[J]. Heterogeneous Catalysis and Fine Chemicals, 1988, 41: 165-170.
  • 8Li N, Huber G W. Aqueous-phase hydrodeoxygenation of sorbitol with Pt/SiO2-Al2O3: Identification of reaction intermediates[J]. Journal of Catalysis, 2010, 270: 48-59.
  • 9Wang K Y, Hawley M C, Furney T D. Mechanism study of sugar and sugar alcohol hydrogenolysis using 1, 3-diol model compounds[J] Industrial & Engineering Chemistry Research, 1995, 34 ( 11 ): 3766-3770.
  • 10Kanie Y, Akiyama K, lwanaoto M. Reaction pathways of glucose and fructose on Pt nanoparticles in subcritical water under a hydrogen atmosphere [J]. Catalysis Today, 2011, 178: 58-63.

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当代化工
2008年 第4期

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