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关于化学反应动力学方程的教学讨论 被引量:3

A Discussion on Teaching of Kinetic Equation of Reaction
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摘要 本文讨论了化学反应动力学方程的一般科学表示形式和反应物出现负级数的可能机制,指出在直链反应的化学反应动力学方程推导教学中应引入链传递过程的循环次数n。 The importance is discussed on the student's mastering general representing form of kinetic equation of reaction in Physical Chemistry course here. Accordingly, possible minus order of some reactants and/or products appearing in the kinetic equation is explained. It is suggested that the recycle numbet (n) of chain reaction should be taken in account for the kinetic equation of the reaction deducing from a possible reaction mechanism.
出处 《化工高等教育》 2008年第4期33-36,共4页 Higher Education in Chemical Engineering
关键词 动力学方程 负级数 直链反应 循环次数n Kinetic equation Minus order Chain reaction Recycle number (n)
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  • 1M K Oudenhuijzen, S van Dommele, J A van Bokhoven, and D C Koningsberger. The kinetics of H/D exchange in cyclopentane [J]. J. Catal, 2003,(214) : 153- 164.
  • 2F Gao, A D Allian, H Zhang, S Cheng, M Garland. Chemical and kinetic study of acetophenone hydrogenation over Pt/Al2O3: Application of BTEM and other multivariate techniques to quantitative on-line FTIR measurements [J]. J. Catal. , 2006,(241): 189-199.
  • 3C. He, M. Paulus, J. Find, J. A. Nickl, H. J. Eberle, J. Spengler, W. Chu, and K. Kohlerm, In situ infrared spectroscopic studies on the mechanism of the selective catalytic reduction of NO by C3H8 over Ga2O3/ Al2O3: High efficiency of the reducing agent [J]. J. Phys. Chem. B, 2005, (109): 15906-15914.

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