熔融法无溶剂一步催化合成四(1,4-二噻英)四氮杂卟啉锰

Solvent-free synthesis of manganese(Ⅱ)-tetra-(1,4-dithiin)-porphyrazine by molten solid method

首次以2,3-二氰基-1,4-二噻英为原料,钼酸铵为催化剂,四水合氯化锰为模板,用熔融法无溶剂一步合成了标题化合物,其结构经过UV-Vis、IR、元素分析、X-射线光电子能谱(XPS)表征。

Complex manganese （ Ⅱ ）-tetra-（ 1, 4-dithiin ）-porphyrazine （MnPz（dtn）4 ） had been synthesized in a solvent-free state from 2,3-dithiolate-1,4-dithiin by molten-solid method using ammonium molybdate as the catalyst in the presence of manganese dichloride tetrahydrate, and the product structure was characterized by UV-vis, FT-IR, elemental analysis and X-ray photoemission spectra.