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Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins

Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins
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摘要 Highly efficient palladium-catalyzed Heck coupling of aryl nonaflates with electron-rich vinyl ethers, and enamides is described. These reactions afforded exclusively the branched products in good yields. The results indicated that aryl nonaflates are effective alternative to the frequently employed aryl triflates. Highly efficient palladium-catalyzed Heck coupling of aryl nonaflates with electron-rich vinyl ethers, and enamides is described. These reactions afforded exclusively the branched products in good yields. The results indicated that aryl nonaflates are effective alternative to the frequently employed aryl triflates.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第9期1017-1020,共4页 中国化学快报(英文版)
基金 the Renmin University of China and the National Natural Science Foundation of China(Nos.20542009 and 20672139)for financial support.
关键词 Aryl nonaflates ELECTRON-RICH PALLADIUM Heck reaction Regioselectivity Aryl nonaflates Electron-rich Palladium Heck reaction Regioselectivity
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