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Cinnamate-functionalized hyperbranched polymer as liquid crystal photo-alignment layer

Cinnamate-functionalized hyperbranched polymer as liquid crystal photo-alignment layer
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摘要 In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer (Boltom-TM H30) to prepare a hyperbranched photosensitive polymer (H30-Ci). The polymer was characterized by UV absorption spectrum and 1H- NMR spectrum. After processed by Linearly Polarized Polymerization (LPP) method, the spin-coated films of H30-Ci were used as photo-alignment layers to assemble liquid crystal (LC) cells containing nematic liquid crystal (5CB). The observation by polarized microscope showed that the H30-Ci blended with a linear polymer (BP-AN-Ci) photo-alignment layers could align LC molecules in a very uniform way. In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer (Boltom-TM H30) to prepare a hyperbranched photosensitive polymer (H30-Ci). The polymer was characterized by UV absorption spectrum and 1H- NMR spectrum. After processed by Linearly Polarized Polymerization (LPP) method, the spin-coated films of H30-Ci were used as photo-alignment layers to assemble liquid crystal (LC) cells containing nematic liquid crystal (5CB). The observation by polarized microscope showed that the H30-Ci blended with a linear polymer (BP-AN-Ci) photo-alignment layers could align LC molecules in a very uniform way.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第9期1131-1134,共4页 中国化学快报(英文版)
基金 the National Natural Science Foundation of China (No. 50103005) Thanks for Professor Shi Wenfang of University of Science and Technology of China to supply the hyperbranched polymer(H30).
关键词 Hyperbranched polymer Photo-alignment layer Linearly polarized polymerization (LPP) Liquid crystal display Hyperbranched polymer Photo-alignment layer Linearly polarized polymerization (LPP) Liquid crystal display
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