摘要
本文首次给出配体，配合物均可生成二聚体的配合物生成反应动力学研究方法。采用改进的二聚常数计算方法给出了多组分的精确解。用本方法研究了三磺化酞菁（Ⅰ）与Ｃｕ（Ⅱ）的反应动力学，结果表明，该反应速率方程为ν＝Ｋ［Ｌ］２［Ｃｕ］
The method for studying kinetics of formation reaction of complex in aggregation system was reported in this paper.The concentration of more than one species was calculated by improved method for calculating dimeration constants.Kinetics of reaction between Cu(Ⅱ) and tri sulfophthalocyanine(S 3Pc) was studied in this way.It shows that the rate of reaction between Cu(Ⅱ) and S 3Pc can be expressed as follows: ν=K[ S 3Pc ]
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1997年第6期93-97,共5页
Spectroscopy and Spectral Analysis
基金
国家江苏省教委自然科学基金
