2,9,16,23-四硝基酞菁镍(Ⅱ)的合成和光谱性质研究

Synthesis and Study on Spectra Properties of the 2,9,16,23-Tetranitrophthalocyanine Nieckel

在强有机碱１，８－二氮杂双环［５．４．０］＋－－７烯（简称ＤＢｕ）存在的醇溶剂中，利用“分子碎片”（４－硝基邻苯二腈）与金属离子通过模板反应的新方法合成了２，９，１６，２３－四硝基酞菁镍（Ⅱ）配合物（简称ＴＮＰｃＮｉ，Ｐｃ＝Ｃ３２Ｈ１２Ｎ８），通过元素分析和ＩＲ光谱进行了表征，研究了配合物在ＤＭＳＯ、ＤＭＦ、Ｐｙ、ＣＨ２Ｃｌ２和Ｃ６Ｈ１２中的电子吸收光谱及荧光光谱。

In the presence of 1,8 diazabicyclo[5.4.0] undec 7 ene(DBu),the 2,9,16,23 tetranitrophthalocyanine nickel has been synthesized by the template reaction of “molecular fragments”(4 nitrophthalonitrile) with metal ions.The compound has been characterized by elemental analysis and IR spectrum.The electronic absorption spectra and fluorescence spectra of the compound in DMSO,DMF,Py,CH 2Cl 2 and C 6H 12 have been measured and studied.