含硼-氮配键漆酚高分子铜 (Ⅱ)配合物的特性及其表征

Formation and Properties of Urushiol Macromolecular Copper(Ⅱ)Complex

含硼－氮配键漆酚高分子与氯化铜的反应产物ＰＵＢＮ－Ｃｕ（Ⅱ）在亚硫酸钠水溶液中能使甲基丙烯酸甲酯于室温下聚合。用红外光谱、Ｘ射线光电子能谱、高效液相色谱等方法对ＰＵＢＮ－Ｃｕ（Ⅱ）进行了表征，并探讨了其引发甲基丙烯酸甲酯聚合的特性和机理。

The PUBN-Cu(Ⅱ) complex is obtained by the reaction of urushiol polymer containing B-N coordinate bond (PUBN) with CuCl2. MMA may be initiated to polymerize by the system of the complex-Na2SO3-H2O at room temperature. The structure and initiating mechanism of the complex are examined by IR, XPS , HPLC.