摘要
Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.
Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.