期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

二维网状冠醚配合物的合成与晶体结构

Two-dimensional Network Crown Ether Complex:Synthesis and Crystal Structure of [K(18-C-6)]_2[Cu(i-mnt)_2]·C_2H_2Cl_2
下载PDF
导出
摘要 以18-冠-6与K2[Cu(i-mnt)2]反应,得到结构新颖的二维网状配合物:[K(18-C-6)]2-[Cu(i-mnt)2]·C2H2Cl2(1).通过元素分析、红外光谱、单晶X-射线衍射对配合物进行了表征.配合物1由两个配阳离子、一个配阴离子和一个C2H2Cl2溶剂分子构成,配合物分子间以N-K键相连接.配合物1的新奇结构在于:配合物中四个配阳离子与两个配阴离子通过K-N键相互连接,形成了一个由36个原子组成的大环.不同的大环相互连接,从而形成二维网状结构. The reaction of 18-crown-6 with K2[Cu（i-mnt）2] afford 2D coordination polymer [K（18-C-6）]2[Cu（i-mnt）2]·C2H2Cl2（1）,the complex 1 has been characterized by elemental analysis,IR and X-ray diffraction analysis. The complex 1 consists of two complex cations [K（18-C-6）]^＋,one complex anion [Cu（i-mnt）2]^2- and one C2H2Cl2 molecule. The complex molecules are linked by N-K interactions.The novel point in the structures of complex 1 is that the two-dimensional network is made up of infinitude 36-member macrocycles formed by N-K interactions between complex cations and anions.
作者 孔令乾 刘海生 李大成 窦建民
机构地区 聊城大学东昌学院 聊城第三中学 聊城大学化学化工学院
出处 《聊城大学学报（自然科学版）》 2008年第2期15-18,共4页 Journal of Liaocheng University:Natural Science Edition
基金 山东省自然科学基金资助项目(Y2003B01)
关键词 冠醚配合物 18-冠-6 二维网状 晶体结构 crown ether complex, 18-crown-6, two-dimensional network,crystal structures
分类号 O626 [理学—有机化学]
  • 相关文献

参考文献12

  • 1王大奇,窦建民,牛梅菊,李大成,刘颖.三维网状冠醚配合物(Bu_4N){[K(18-C-6)][Cd_4(dmit)_2(dmt)_3]}的合成与结构[J].化学学报,2003,61(4):551-555. 被引量：6
  • 2[4]WOLF C,HUMMEL H U.The crystal structure of calcium 1,1-dicyanoethylene-2,2-dithiolate pentahydrate[J].Dalton Trans.,1986,43～48.
  • 3[5]XIONG R G,LIU C,YOU X Z,et al.A novel tris(Lewis base)adduct.[(dimercaptomethylene)propane-dinitrilato-S,S']tris(3methyl-pyridine)zinc(Ⅱ)[J].Polyhedron,1997,16(10):1 637～1 641.
  • 4[6]XIONG R G,ZUO J L,YOU X Z,et al.A novel dimeric zinc complex:bis{-(dimercaptomethylene)propanedinitrilatos,S']}tetrakis(4-methylpyridine)dizinc(Ⅱ)-chloroform[J].Inorg.Chem,1997,36:2 472～2 480.
  • 5[7]GELDER J I.ENEMARK J H.Crystal and molecular structure of tetra-n-butylammonium di-mu.-sulfido-bis(oxo-1,1-dicyanoethylene-2,2-dithiolatomolybdate(V)).[(n-C4H9)4N]2[Mo2O2S2(S2C2(CN)2)2][J].Inorg.Chem,1976.15:1 839～1845.
  • 6[8]LIU C W,STAPLES R J,FACKLER J P.Copper(I)1,1-dithiolate cluster transformations.Synthesis of[BuN]6[Cu6(S,i-MNT)6],imnt=[S2CC(CN)2]-,from[Bu4N]4[Cu8(i-mnt)6]with sulfur.Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral[Bu4N]4[Cu4(i-mnt)4]which oxidizes in solution to give the homoeubane[Bu4N]4[Cu8(i-mnt)6]and[Bu4N]2[Cu(imnt)2][J].Coord.Chem.Rev.,1998,174:147～177.
  • 7[9]PAUL J M,BIRKER W L.Synthesis and X-ray crystal structure of a 1,1-dithiolate cluster compound containing a cube of eight Ag1atoms,[AgI8{S2C C(CN)2}6]4-[J].Chem.Comm.,1981,322.
  • 8[10]KHAN M N,FACKLER J P.KING J C,et al.Synthesis and characterization of the luminescent dithiolate-bridged dimer[n-Bu4N]2[Au(i-MNT)]2(i-MNT=S2C2(CN)2)and its structurally characterized,metal-metal-bonded gold(Ⅱ)oxidation product[Ph4As]2[Au(i-MNT)Cl]2[J].Inorg.Chem.,1988,27:1 672～1 673.
  • 9[11]FACKLER J P,STAPLES R J,ASSEFA Z,et al.Synthesis and structural characterisation of[(pta)3Au]2Au2(i-mnt)2·0.5Me2Co·0.5MeCN:an example of unsupported Au I Au I interactions with[Au(pta)3]+,giving a non-linear tetranuclear chain{pta=phosphatriazaadamantane,i-rant＝[S2C2(CN)2]2}[J].Chem.Comm.,1994,431～438.
  • 10[12]LONG D L,CUI Y,CHEN J T,et al.One-dimensional co-ordination polymers formed by crown ether metal cation bridges:synthesis and crystal structure of nickeI(Ⅱ)dithiolene complexes[(Na(benzo-15-crown-5)}2Ni(i-mnt)2]n·nCH2C12 and[{Na(benzo-15-crown-5)}2Ni(mnt)2]n[J].Polyhedron.1998,17:3 969～3 978.

二级参考文献27

  • 1(a) Yaghi, O. M.; Li, H.; Davis, C.; Richardson, D.; Groy,T. L. Acc. Chem. Res. 1998, 31, 474.(b) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew.Chem., Int. Ed. 1999, 38, 2639.(c) Zaworotko, M. J. Chem. Commun. 2001, 1.(d) Fujita, M.; Umemoto, K.; Yoshizawa, M.; Fujita, N.;Kusukawa, T.; Biradha, K. Chem. Commun. 2001, 509.(e) Zhu, D.-Z.; Wang, T.; Song, X.-M.; Dou, J.-M.; Li,D.-C.; Wang, D.-Q.; Wu, M.-M.; Gao, Y.-Q. Acta Chim.Sinica 2002, 60, 910 (in Chinese).(朱德中,王彤,宋兴民,窦建民,李大成,王大奇,武梅梅,高玉芹,化学学报,2002,60,910.)
  • 2(a) Etler, M. C. Acc. Chem. Res. 1990, 23, 120.(b) Desirju, G. R. J. Chem. Soc., Dalton Trans. 2000,3745.(c) Braga, D.; Gresioni, F. Acc. Chem. Res. 2000, 33,601.
  • 3(a) Ma, J. C.; Dougherty, D. A. Chem. Rev. 1997, 97,1303.(b) Dou, J.-M.; Liu, Y.; Sun, D.-Z.; Li, X.; Zheng, P.-J.; Du, C.-X.; Zhu, Y. Acta Chim. Sinica 2001, 59,918 (in Chinese).(窦建民,刘颖,孙得志,李雪,郑培菊,杜晨霞,朱玉,化学学报,2001,59,918.)
  • 4(a) Zhu, D.-Z.; Song, X.-M.; Dou, J.-M.; Liu, Y.; Wang,D.-Q. Chin. J. Chem. 2002, 20, 424.(b) Ye, B.-H.; Chen, X.-M.; Xue, G.-Q.; Ji, L.-N. J.Chem. Soc., Dalton Trans. 1998, 2827.(c) Kuroda-Sowa, T.; Munakata, M.; Matsuda, H.; Akiyama,S.; Maekawa, M. J. Chem. Soc., Dalton Trans. 1995, 2201.
  • 5Hazell, A.; Hazell, R. G.; Holm, M. F.; Krogh, L. Acta Crystallogr. 1991, 47B, 234.
  • 6Hazell, A.; Hazell, R. G. Acta Crystallogr. 1991, 47C, 730.
  • 7Roger, R. D.; Bond, A. H. Inorg. Chim. Acta 1996, 250,117.
  • 8Zhang, H.; Wang, X.-M.; Zhang, K.-C.; Teo, B. K. Inorg.Chem. 1998, 37, 3490.
  • 9Zhang, H.; Wang, X.-M.; Zhu, H.; Xiao, W.; Teo, B. K.J. Am. Chem. Soc. 1997, 119, 5463.
  • 10Zhang, H.; Wang, X.-M.; Teo, B. K. J. Am. Chem. Soc.1996, 118, 11813.

共引文献5

聊城大学学报（自然科学版）
2008年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部