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新型线性三核锰(Ⅱ)配合物的最小及最佳纳米颗粒结构表征及计算

Calculation and Structural Characteristic of the Minimum and Optimum Nano-particles of a New Trinuclear Manganese(Ⅱ) Complex
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摘要 从新型线性三核锰(Ⅱ)配合物的晶体结构入手,对配合物的最小纳米颗粒提出假设,并通过配合物不同粒径尺度的晶胞数、原子数及表面原子数占总原子数的比例进行计算分析,探讨其相关规律,确定其最佳纳米尺度为100nm,为纳米颗粒的制备提供一定理论依据。 Based on Nanomaterials and crystal chemistry knowledge, an assumption of the minimum dimension of the new trinuclear manganese(Ⅱ) complex was proposed, according to the crystal structure. Through calculation the number of the different size of crystal cells, atomicity and the external atomicity in the total number, the characteristics of nanostructure parameters were obtained. Meanwhile, defined the optimum dimension of the trinuclear manganese (Ⅱ) complex is 100nm ,by means of the analysis of the curves ,which offered certain theoretical foundation to the preparation of nanoparticles.
出处 《纳米科技》 2008年第4期8-11,22,共5页
关键词 三核锰(Ⅱ)配合物 晶体结构 纳米颗粒 trinuclear manganese(Ⅱ) complex crystal structure nanometer
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